Jump to ContentJump to Main Navigation
Show Summary Details
More options …

Radiochimica Acta

International Journal for chemical aspects of nuclear science and technology

Editor-in-Chief: Qaim, Syed M.

12 Issues per year


IMPACT FACTOR 2017: 1.202

CiteScore 2017: 1.22

SCImago Journal Rank (SJR) 2017: 0.409
Source Normalized Impact per Paper (SNIP) 2017: 0.869

Online
ISSN
2193-3405
See all formats and pricing
More options …
Volume 102, Issue 12

Issues

In-situ formation, thermal decomposition, and adsorption studies of transition metal carbonyl complexes with short-lived radioisotopes

Julia Even
  • Corresponding author
  • Johannes Gutenberg-Universität Mainz, 55099 Mainz, Germany
  • Helmholtz-Institut Mainz, 55099 Mainz, Germany
  • Email
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Alexander Yakushev / Christoph Emanuel Düllmann
  • Johannes Gutenberg-Universität Mainz, 55099 Mainz, Germany
  • Helmholtz-Institut Mainz, 55099 Mainz, Germany
  • GSI Helmholtzzentrum für Schwerionenforschung GmbH, 64192 Darmstadt, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Jan Dvorak / Robert Eichler
  • Paul Scherrer Institut, 5232 Villigen, Switzerland
  • University of Bern, 3012 Bern, Switzerland
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Oliver Gothe / Willy Hartmann / Daniel Hild / Egon Jäger / Jadambaa Khuyagbaatar
  • Helmholtz-Institut Mainz, 55099 Mainz, Germany
  • GSI Helmholtzzentrum für Schwerionenforschung GmbH, 64192 Darmstadt, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Birgit Kindler / Jens Volker Kratz / Jörg Krier / Bettina Lommel / Lorenz Niewisch / Heino Nitsche / Inna Pysmenetska / Matthias Schädel / Brigitta Schausten / Andreas Türler
  • Paul Scherrer Institut, 5232 Villigen, Switzerland
  • University of Bern, 3012 Bern, Switzerland
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Norbert Wiehl
  • Johannes Gutenberg-Universität Mainz, 55099 Mainz, Germany
  • Helmholtz-Institut Mainz, 55099 Mainz, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ David Wittwer
  • Paul Scherrer Institut, 5232 Villigen, Switzerland
  • University of Bern, 3012 Bern, Switzerland
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2014-08-07 | DOI: https://doi.org/10.1515/ract-2013-2198

Abstract

We report on the in-situ synthesis of metal carbonyl complexes with short-lived isotopes of transition metals. Complexes of molybdenum, technetium, ruthenium and rhodium were synthesized by thermalisation of products of neutron-induced fission of 249Cf in a carbon monoxide-nitrogen mixture. Complexes of tungsten, rhenium, osmium, and iridium were synthesized by thermalizing short-lived isotopes produced in 24Mg-induced fusion evaporation reactions in a carbon monoxide containing atmosphere. The chemical reactions took place at ambient temperature and pressure conditions. The complexes were rapidly transported in a gas stream to collection setups or gas phase chromatography devices. The physisorption of the complexes on Au and SiO2 surfaces was studied. We also studied the stability of some of the complexes, showing that these start to decompose at temperatures above 300 ℃ in contact with a quartz surface. Our studies lay a basis for the investigation of such complexes with transactinides.

This article offers supplementary material which is provided at the end of the article.

Keywords: Carbonyl Complexes; Short-lived Isotopes; Carbonyl Synthesis; In-Situ Synthesis; Adsorption Studies; Thermochromatography; Isothermal Chromatography; Thermal Stability; Fission Products; Superheavy Elements; Physical Preseparation

Supplementary material

the online version of this article (DOI: 10.1515/ract-2013-2198) provides supplementary material for authorized users.

About the article

Accepted: 2014-06-13

Received: 2013-10-09

Published Online: 2014-08-07

Published in Print: 2014-12-28


Citation Information: Radiochimica Acta, Volume 102, Issue 12, Pages 1093–1110, ISSN (Online) 2193-3405, ISSN (Print) 0033-8230, DOI: https://doi.org/10.1515/ract-2013-2198.

Export Citation

©2014 Walter de Gruyter Berlin/Boston.Get Permission

Supplementary Article Materials

Citing Articles

Here you can find all Crossref-listed publications in which this article is cited. If you would like to receive automatic email messages as soon as this article is cited in other publications, simply activate the “Citation Alert” on the top of this page.

[1]
V. Pershina and M. Iliaš
The Journal of Chemical Physics, 2018, Volume 149, Number 20, Page 204306
[2]
V. Pershina and M. Iliaš
The Journal of Chemical Physics, 2017, Volume 146, Number 18, Page 184306
[3]
Julia Even and D. Rudolph
EPJ Web of Conferences, 2016, Volume 131, Page 07008
[4]
Robert Eichler, M. Asai, H. Brand, N.M. Chiera, A. Di Nitto, R. Dressler, Ch.E. Düllmann, J. Even, F. Fangli, M. Goetz, H. Haba, W. Hartmann, E. Jäger, D. Kaji, J. Kanaya, Y. Kaneya, J. Khuyagbaatar, B. Kindler, Y. Komori, B. Kraus, J.V. Kratz, J. Krier, Y. Kudou, N. Kurz, S. Miyashita, K. Morimoto, K. Morita, M. Murakami, Y. Nagame, K. Ooe, D. Piguet, N. Sato, T.K. Sato, J. Steiner, P. Steinegger, T. Sumita, M. Takeyama, K. Tanaka, T. Tomitsuka, A. Toyoshima, K. Tsukada, A. Türler, I. Usoltsev, Y. Wakabayashi, Y. Wang, N. Wiehl, Y. Wittwer, A. Yakushev, S. Yamaki, S. Yano, S. Yamaki, Z. Qin, and D. Rudolph
EPJ Web of Conferences, 2016, Volume 131, Page 07005
[5]
Shiwei Cao, Yang Wang, Zhi Qin, Fangli Fan, Hiromitsu Haba, Yukiko Komori, Xiaolei Wu, Cunmin Tan, and Xin Zhang
Phys. Chem. Chem. Phys., 2016, Volume 18, Number 1, Page 119
[6]
Andreas Türler, Robert Eichler, and Alexander Yakushev
Nuclear Physics A, 2015, Volume 944, Page 640
[7]
Yang Wang, Zhi Qin, Fang-Li Fan, Hiromitsu Haba, Yukiko Komori, Shi-Wei Cao, Xiao-Lei Wu, and Cun-Min Tan
Phys. Chem. Chem. Phys., 2015, Volume 17, Number 20, Page 13228

Comments (0)

Please log in or register to comment.
Log in