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Radiochimica Acta

International Journal for chemical aspects of nuclear science and technology

Editor-in-Chief: Qaim, Syed M.


IMPACT FACTOR 2018: 1.339

CiteScore 2018: 1.20

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2193-3405
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Volume 107, Issue 7

Issues

Recent developments in resonance ionization mass spectrometry for ultra-trace analysis of actinide elements

Sebastian Raeder
  • Corresponding author
  • Institut für Physik, Johannes Gutenberg-Universität Mainz, 55099 Mainz, Germany
  • Helmholtz-Institut Mainz, 55099 Mainz, Germany
  • GSI Gesellschaft für Schwerionenforschung GmbH, 64291 Darmstadt, Germany
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/ Nina Kneip / Tobias Reich / Dominik Studer / Norbert Trautmann / Klaus Wendt
Published Online: 2019-06-01 | DOI: https://doi.org/10.1515/ract-2019-0001

Abstract

Resonance ionization mass spectrometry is an efficient tool to detect minute amounts of long-lived radio-isotopes in environmental samples. Applying resonant excitation and ionization with pulsed laser radiation within a hot cavity atomizer enables the sensitive detection and precise quantification of long-lived actinide isotopes. Due to the inherently element selective ionization process, this method ensures ultimate suppression of contaminations from other elements and molecules. The characterization of in-source resonance ionization of the actinide elements U, Th, Np, and Am using a compact quadrupole mass spectrometer (QMS) setup are discussed.

Keywords: Resonance ionization; mass spectrometry; RIMS; trace analysis; actinides

Dedicated to the memory of Professor Günter Herrmann.

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About the article

Received: 2018-12-27

Accepted: 2019-05-02

Published Online: 2019-06-01

Published in Print: 2019-07-26


Funding Source: Bundesministerium für Bildung und Forschung

Award identifier / Grant number: 05P12UMCIA

This work was supported by the Bundesministerium für Bildung und Forschung (BMBF, Germany) under the consecutive projects 05P12UMCIA, Funder Id: http://dx.doi.org/10.13039/501100002347 and 05P15UMCIA, Funder Id: http://dx.doi.org/10.13039/501100002347 as well as by the project 02NUK044B, Funder Id: http://dx.doi.org/10.13039/501100002347. Additional funds were provided by the Deutsche Forschungsgemeinschaft (DFG) within the framework of the interdisciplinary research training group GRK 826, Funder Id: http://dx.doi.org/10.13039/501100001659 “Spurenanalytik von Elementspezies: Methodenentwicklungen und Anwendungen”.


Citation Information: Radiochimica Acta, Volume 107, Issue 7, Pages 645–652, ISSN (Online) 2193-3405, ISSN (Print) 0033-8230, DOI: https://doi.org/10.1515/ract-2019-0001.

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