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Reviews in Inorganic Chemistry

Editor-in-Chief: Schulz, Axel

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Volume 36, Issue 3

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Structural chemistry of anionic fluoride and mixed-ligand fluoride complexes of indium(III)

Ruven L. Davidovich
  • Corresponding author
  • Institute of Chemistry, Far-Eastern Branch, Russian Academy of Sciences, 159 Prospect 100-Letiya Vladivostoka, Vladivostok 690022, Russian Federation
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/ Pavel P. Fedorov
  • Corresponding author
  • General Physics Institute, Russian Academy of Sciences, 38 Vavilov Street, Moscow 119991, Russian Federation
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/ Artur I. Popov
Published Online: 2016-02-27 | DOI: https://doi.org/10.1515/revic-2015-0019

An erratum for this article can be found here: https://doi.org/10.1515/revic-2016-0009

Abstract

A total of 88 crystal lattice structures of indium(III) anionic fluoride and mixed-ligand fluoride complexes have been discussed and systematized. Most of these structures have been established by single-crystal X-ray diffraction techniques, but some were characterized by powder X-ray diffraction methods. The presented crystallography data were compared with known isotypical compounds. This paper offers a discussion of the geometry of indium and outer sphere cation coordination polyhedra; the association of indium atoms in dimer, oligomer, and polymer formations (chains, layers, frameworks); types of cation-anion interactions; and their contributions in actual three-dimensional crystal structures including types of the crystal lattices formed. We also used structural examples of potassium fluoroindates(III) to describe the basics of the structural depolymerization model for fluoride compounds, which is used to depict the formation and transformation of complex metal fluorides and predict structural types of novel or uncharacterized fluorides in the corresponding compound series. For the readers’ convenience, we have compiled structural information in a single table containing phase compositions and corresponding standard crystallographic data (such as crystal system, space group, unit cell parameters, number of formula units per cell [Z], reliability factors [R], and In-F and In-O bond lengths).

Keywords: coordination number; crystal structure; fluoride complex; fluoroindate(III); indium(III); mixed-ligand; polyhedron

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About the article

Ruven L. Davidovich

Ruven L. Davidovich graduated from Kishinev University, Moldova in 1955, received his PhD degree from Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia in 1966 under the supervision of Prof. Yuri A. Buslaev, and obtained his Dr. Sci. habilitation in 1993. He joined the Institute of Chemistry, Far-Eastern Branch, Russian Academy of Sciences, Vladivostok, Russia in 1958. His research interests focus on the synthesis and properties of fluoride and chelate complexes of Group III-V metals.

Pavel P. Fedorov

Pavel P. Fedorov graduated from the Lomonosov Moscow Institute of Fine Chemical Technology in 1972, received his PhD degree from Shubnikov Institute of Crystallography, Russian Academy of Sciences, Moscow, Russia in 1977 under the supervision of Prof. Kh. S. Bagdasarov, and obtained his Dr. Sci. habilitation in 1991. He joined Prokhorov General Physics Institute, Russian Academy of Sciences, Moscow, Russia in 2003. His research interests focus on the synthesis and properties of transition metal fluorides and fluoride optical materials.

Artur I. Popov

Artur I. Popov graduated from the Lomonosov Moscow State University in 1985 and received his PhD degree from the same university in 1988 under the supervision of Prof. Victor I. Spitsyn. He joined Cardinal Intellectual Property, Inc. in 2014. His scientific interests focus on the synthesis and properties of inorganic fluorides and chemical informatics.


Received: 2015-11-26

Accepted: 2016-01-20

Published Online: 2016-02-27

Published in Print: 2016-10-01


Citation Information: Reviews in Inorganic Chemistry, Volume 36, Issue 3, Pages 105–133, ISSN (Online) 2191-0227, ISSN (Print) 0193-4929, DOI: https://doi.org/10.1515/revic-2015-0019.

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