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Science and Engineering of Composite Materials

Editor-in-Chief: Hoa, Suong V.

Editorial Board Member: Hamada, Hiroyuki / Brandt, Andrzej M. / Duc, Nguyen Dinh / Ehrenstein, Gottfried Wilhelm / Hui, David / Lee, L. James / Medraj, Mamoun / Nakai, Asami / Nicolais, Luigi / Seferis, James C. / Tan, Kiang Hwee / Ton-That, Minh Tan / Xiao, Xinran / Zako, Masaru / Zhong, W.H. Katie

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Online
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2191-0359
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Volume 18, Issue 3 (Sep 2011)

Issues

Optical limiters based on silver nanoparticles embedded in amorphous polystyrene

Gianfranco Carotenuto
  • Institute of Composite and Biomedical Materials, National Research Council, Piazzale Tecchio, 80, 80125 Napoli, Italy
  • Email:
/ Mariano Palomba
  • Institute of Composite and Biomedical Materials, National Research Council, Piazzale Tecchio, 80, 80125 Napoli, Italy
/ Angela Longo
  • Institute of Composite and Biomedical Materials, National Research Council, Piazzale Tecchio, 80, 80125 Napoli, Italy
/ Sergio De Nicola
  • National Institute of Optics, National Research Council, Via Campi Flegrei, 34, 80078 Pozzuoli, Italy
/ Luigi Nicolais
  • Institute of Composite and Biomedical Materials, National Research Council, Piazzale Tecchio, 80, 80125 Napoli, Italy
Published Online: 2011-09-07 | DOI: https://doi.org/10.1515/secm.2011.030

Abstract

A simple technique to prepare plastic color-filters based on the surface plasmon resonance (SPR) of silver nanoparticles has been developed. In particular, silver/polystyrene nanocomposites have been prepared by dissolving silver acetylacetonate in amorphous polystyrene and heating the obtained solid solution at a convenient temperature (ca. 200°C). When the metal precursor decomposes, the produced silver atoms diffuse into the polymeric matrix and clusterize, leading to the formation of a contact-free dispersion of hyperfine silver phase. The obtained films have been characterized by UV-VIS spectroscopy and the optical extinction spectra have been fitted by the Mie’s theory, introducing the limitation of the mean free path due to the collisions of conduction electrons with the boundary of the nanoparticles.

Keywords: nanocomposites; optical filters; polystyrene; silver acetylacetonate; silver nanoparticles; surface plasmon resonance; thermolysis

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Corresponding author


Published Online: 2011-09-07

Published in Print: 2011-09-01


Citation Information: Science and Engineering of Composite Materials, ISSN (Online) 2191-0359, ISSN (Print) 0792-1233, DOI: https://doi.org/10.1515/secm.2011.030. Export Citation

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[2]
T. Křenek, T. Kovářík, M. Pola, I. Jakubec, P. Bezdička, Z. Bastl, D. Pokorná, M. Urbanová, A. Galíková, and J. Pola
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