Jump to ContentJump to Main Navigation
Show Summary Details
More options …

Science and Engineering of Composite Materials

Editor-in-Chief: Hoa, Suong V.

Editorial Board: Hamada, Hiroyuki / Brandt, Andrzej M. / Duc, Nguyen Dinh / Ehrenstein, Gottfried Wilhelm / Hui, David / Lee, L. James / Medraj, Mamoun / Nakai, Asami / Nicolais, Luigi / Seferis, James C. / Tan, Kiang Hwee / Ton-That, Minh Tan / Xiao, Xinran / Zako, Masaru / Zhong, W.H. Katie

6 Issues per year


IMPACT FACTOR 2016: 0.480
5-year IMPACT FACTOR: 0.542

CiteScore 2017: 1.82

SCImago Journal Rank (SJR) 2017: 0.540
Source Normalized Impact per Paper (SNIP) 2017: 0.876

Online
ISSN
2191-0359
See all formats and pricing
More options …
Volume 23, Issue 6

Issues

Effect of polyarylene ether nitrile on the curing behaviors and properties of bisphthalonitrile

Zhiran Chen
  • Research Branch of Functional Materials, Institute of Microelectronic and Solid State Electronic, University of Electronic Science and Technology of China, Chengdu 610054, P.R. China
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Yajie Lei
  • Research Branch of Functional Materials, Institute of Microelectronic and Solid State Electronic, University of Electronic Science and Technology of China, Chengdu 610054, P.R. China
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Hailong Tang
  • Research Branch of Functional Materials, Institute of Microelectronic and Solid State Electronic, University of Electronic Science and Technology of China, Chengdu 610054, P.R. China
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Xiaobo Liu
  • Corresponding author
  • Research Branch of Functional Materials, Institute of Microelectronic and Solid State Electronic, University of Electronic Science and Technology of China, Chengdu 610054, P.R. China
  • Email
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2016-10-14 | DOI: https://doi.org/10.1515/secm-2013-0235

Abstract

The 2,2-bis[4-(3,4)-dicyanophenoxy phenyl]propane (BAPh)/polyarylene ether nitrile (PEN-OH) prepolymers and polymers were prepared by heat polymerization. Firstly, BAPh/PEN-OH systems were characterized using differential scanning calorimetry, dynamic rheological analysis, and thermal gravimetric analysis. The results revealed that the polymerization reaction can be controlled by various concentrations of PEN-OH and postcuring temperatures, and BAPh/PEN-OH prepolymers had low curing temperatures (229.3–300.4°C), large processing windows (∼106.5°C) with low melt viscosities, and excellent thermal stabilities. Then, the polymerization reaction and surface structures of BAPh/PEN-OH systems were investigated using Fourier transform infrared and scanning electron microscopy, respectively. The interpenetrating polymer networks were found in BAPh/PEN-OH polymers, suggesting that the addition of PEN-OH can not only promote the curing behaviors of BAPh but also increase the toughness of the polymers. The flexure strength and modulus of BAPh/PEN-OH polymers increased with the introduction of PEN-OH. The dielectric properties of BAPh/PEN-OH polymers were investigated, which had little dependence on the frequency. BAPh/PEN-OH systems can be used as a good candidate for high-performance polymeric materials.

Keywords: bisphthalonitrile; mechanical properties; polyarylene ether nitrile; polymerization; thermal properties

References

  • [1]

    Zhang CH, Wei HG, Liu YY, Guo ZH. High. Perform. Polym. 2012, 8, 702–709.Google Scholar

  • [2]

    Guo H, Zhou YK, Cheng ZR, Zhang JD, Zhan YQ, Yang J, Liu XB. High. Perform. Polym. 2012, 24, 571–579.Google Scholar

  • [3]

    Zhang BX, Luo ZH, Zhou H, Liu F, Yu RL, Pan YX, Wang Y, Zhao T. High. Perform. Polym. 2012, 5, 398–404.Google Scholar

  • [4]

    Keller TM. J. Polym. Sci. Part A Polym. Chem. 1997, 26, 3199–3212.Google Scholar

  • [5]

    Sumner MJ, Sankarapandian M, McGrath JE, Riffle JS, Sorathia U. Polymer 2002, 43, 5069–5076.Google Scholar

  • [6]

    Dominguez DD, Keller TM. J. Appl. Polym. Sci. 2008, 110, 2504–2515.Google Scholar

  • [7]

    Sastri SB, Armistead JP, Keller TM. Polym. Compos. 1996, 17, 816–822.Google Scholar

  • [8]

    Brunovska Z, Lyon R, Ishida H. Thermochim. Acta 2000, 357, 195–203.Google Scholar

  • [9]

    Keller TM. J. Polym. Sci. Part A Polym. Chem. 1997, 26, 3199–3212.Google Scholar

  • [10]

    Sastri SB, Keller TM. J. Polym. Sci. Part A Polym. Chem. 1999, 37, 2105–2111.Google Scholar

  • [11]

    Cao GP, Chen WJ, Liu XB. Polym. Degrad. Stabil. 2008, 93, 739–744.Google Scholar

  • [12]

    Keller TM. Chem. Mater. 1993, 6, 302–305.Google Scholar

  • [13]

    Laskoski M, Keller TM, Qadri SB. Polymer 2007, 48, 7484–7489.Google Scholar

  • [14]

    Lei YJ, Zuo F, Zhao R, Liu XB. J. Mater. Eng. 2009, s2, 1001–4381.Google Scholar

  • [15]

    Yang XL, Zhang JD, Lei YJ, Zhong JC, Liu XB. J. Appl. Polym. Sci. 2011, 121, 2331–2337.Google Scholar

  • [16]

    Wirasate S, Dhumrongvaraporn S, Allen DJ, Ishida H. J. Appl. Polym. Sci. 1998, 7, 1299–1306.Google Scholar

  • [17]

    Huang X, Pu ZJ, Tong LF, Wang ZC, Liu XB. J. Mater. Sci. Mater. Electron. 2012, 23, 2089–2097.Google Scholar

  • [18]

    Tang HL, Yang J, Zhong JC, Zhao R, Liu XB. Mater. Lett. 2011, 65, 1703–1706.Google Scholar

  • [19]

    Li C, Gu Y, Liu XB, Zou YB, Tang AB. Thin Solid Films 2006, 515, 1872–1876.Google Scholar

  • [20]

    Wang JY, Wang MJ, Liu C, Zhou HX, Jian XG. Polym. Bull. 2013, 70, 1467–1481.Google Scholar

  • [21]

    Zhao X, Guo H, Lei YJ, Zhao R, Zhong JC, Liu XB. J. Appl. Polym. Sci. 2012, 6, 4873–4878.Google Scholar

  • [22]

    Frisch HL. Polym. Int. 1985, 2, 149–153.Google Scholar

  • [23]

    Lipatov YS. Prog. Polym. Sci. 2002, 9, 1721–1801.Google Scholar

  • [24]

    Jia LY, Zhang C, Du ZJ, Li CJ, Li HQ. Polym. J. 2007, 39, 593–597.Google Scholar

  • [25]

    Laskoski M, Dominguez DD, Keller TM. ACS Symp. Ser. 2005, 922, 378–388.Google Scholar

  • [26]

    Zhou YK, Yang J, Zhan YQ, Yang XL, Zhong JC, Zhao R, Liu XB. J. Appl. Polym. Sci. 2012, 5, 3829–3835.Google Scholar

  • [27]

    Du RH, Li WT, Liu XB. Polym. Degrad. Stabil. 2009, 12, 2178–2183.Google Scholar

  • [28]

    Keller TM. Chem. Mater. 1994, 6, 302–305.Google Scholar

  • [29]

    Seoudi R, El-Bahy GS, El Sayed ZA. J. Mol. Struct. 2005, 753, 119–126.Google Scholar

  • [30]

    Chen ZR, Guo H, Tang HL, Yang XL, Xu MZ, Liu XB. J. Appl. Polym. Sci. 2013, 129, 2621–2628.Google Scholar

  • [31]

    Guo H, Lei YJ, Zhao X, Yang XY, Zhao R, Liu XB. J. Appl. Polym. Sci. 2012, 125, 649–656.Google Scholar

  • [32]

    Keller TM, Griffith JR. ACS Org. Coat. Plast. Chem. Prep. 1980, 43, 804–807.Google Scholar

  • [33]

    Xu MZ, Yang XL, Zhao R, Liu XB. J. Appl. Polym. Sci. 2013, 2, 1176–1184.Google Scholar

  • [34]

    Laza JM, Vilas JL, Mijangos F, Rodriguez M, Leon LM. J. Appl. Polym. Sci. 2005, 98, 818–824.Google Scholar

About the article

Received: 2013-09-24

Accepted: 2014-07-22

Published Online: 2016-10-14

Published in Print: 2016-11-01


Citation Information: Science and Engineering of Composite Materials, Volume 23, Issue 6, Pages 579–588, ISSN (Online) 2191-0359, ISSN (Print) 0792-1233, DOI: https://doi.org/10.1515/secm-2013-0235.

Export Citation

©2016 Walter de Gruyter GmbH, Berlin/Boston.Get Permission

Comments (0)

Please log in or register to comment.
Log in