Zeitschrift für Kristallographie - Crystalline Materials
Editor-in-Chief: Pöttgen, Rainer
Ed. by Antipov, Evgeny / Bismayer, Ulrich / Boldyreva, Elena V. / Huppertz, Hubert / Petrícek, Václav / Tiekink, E. R. T.
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Phänomenologische Theorie der Kristallabscheidung an Oberflächen. I
Citation Information: Zeitschrift für Kristallographie. Volume 110, Issue 1-6, Pages 372–394, ISSN (Online) 0044-2968, ISSN (Print) 1433-7266, DOI: https://doi.org/10.1524/zkri.1958.110.1-6.372, July 2010
- Published Online:
Crystallization on surfaces is discussed thermodynamically. Of the three different growth mechanisms, that of growth atom-layer by atom-layer through surface nucleation (Frank-van der Merwe mechanism) occurs only for growth on material of the same composition. The growth on a different material, on the other hand, occurs, in general, by original formation of a mono- or polymolecular layer without nucleation, which then leads to formation of three-dimensional nuclei (Stranski-Krastanov mechanism), or through the formation of three-dimensional nuclei directly on the foreign substrate (Volmer-Weber mechanism) where the form and size of the nucleus cannot, in general, be determined by the Wulff-Gibbs law.
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