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Zeitschrift für Kristallographie - Crystalline Materials

Editor-in-Chief: Pöttgen, Rainer

Ed. by Antipov, Evgeny / Bismayer, Ulrich / Boldyreva, Elena V. / Friese, Karen / Huppertz, Hubert / Tiekink, E. R. T.

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Volume 117, Issue 5-6

Issues

Polymorphic forms of bismuth phosphate

Rose C. L. Mooney-Slater
Published Online: 2010-07-28 | DOI: https://doi.org/10.1524/zkri.1962.117.5-6.371

Abstract

Bismuth phosphate has long been known to crystallize with the monazite-type structure. It is now possible to report the existence of two other modifications, and to describe their crystal structure. One type is hexagonal, and has the CePO4 · ½ H2O structure. The other is a monoclinic high-temperature form which very slowly converts to the monazite-type structure at ordinary temperatures. The structure of the hexagonal crystal has been determined from Weissenberg single-crystal data, and that of the high-temperature form from powder-diffraction data. The three structures preserve certain features in common, and intercomparison seems to indicate that the transformation from one to the other must be predominantly displacive rather than disruptive in character.

About the article

Published Online: 2010-07-28

Published in Print: 1962-12-01


Citation Information: Zeitschrift für Kristallographie, Volume 117, Issue 5-6, Pages 371–385, ISSN (Online) 0044-2968, ISSN (Print) 1433-7266, DOI: https://doi.org/10.1524/zkri.1962.117.5-6.371.

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