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Zeitschrift für Kristallographie - Crystalline Materials

Editor-in-Chief: Pöttgen, Rainer

Ed. by Antipov, Evgeny / Bismayer, Ulrich / Boldyreva, Elena V. / Friese, Karen / Huppertz, Hubert / Tiekink, E. R. T.

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Volume 126, Issue 1-3


Revised crystal structure of dehydrated Na-Type A zeolite

J. V. Smith / L. G. Dowell
Published Online: 2010-07-28 | DOI: https://doi.org/10.1524/zkri.1968.126.1-3.135


The structure determined earlier from x-ray powder diffraction data has been confirmed but changed in detail by new data obtained for a tiny single crystal. Na(1) is displaced 0.4 Å into the large cavity from the center of a ring of six oxygen atoms, resulting in effective three-fold coordination with three oxygen atoms at 2.3 Å and three others at 3.0 Å. Na(2) is displaced 1 Å, nearly in the plane of the ring, from the center of a ring of eight oxygen atoms. The coordination is even more unusual with oxygen atoms at 2.5, 3.0, 3.4, 4.0 and 4.1 Å.

About the article

Published Online: 2010-07-28

Published in Print: 1968-01-01

Citation Information: Zeitschrift für Kristallographie, Volume 126, Issue 1-3, Pages 135–142, ISSN (Online) 0044-2968, ISSN (Print) 1433-7266, DOI: https://doi.org/10.1524/zkri.1968.126.1-3.135.

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