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Zeitschrift für Kristallographie - Crystalline Materials

Editor-in-Chief: Pöttgen, Rainer

Ed. by Antipov, Evgeny / Bismayer, Ulrich / Boldyreva, Elena V. / Huppertz, Hubert / Petrícek, Václav / Tiekink, E. R. T.

12 Issues per year


IMPACT FACTOR 2016: 3.179

CiteScore 2016: 3.30

SCImago Journal Rank (SJR) 2016: 1.097
Source Normalized Impact per Paper (SNIP) 2016: 2.592

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2196-7105
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Volume 134, Issue 1-2 (Aug 1971)

Issues

The crystal chemistry of diaboleite*

Roland C. Rouse
Published Online: 2010-07-28 | DOI: https://doi.org/10.1524/zkri.1971.134.1-2.69

Abstract

Diaboleite, Pb2Cu(OH)4Cl2, is tetragonal, P4mm, with a = 5.870 Å and c = 5.494 Å. The structure has been refined by the method of least squares to a conventional R value of 5.0%. Diaboleite is a derivative of the cubic perovskite structure, ABO3, with Cu and possibly Cl vacancies. The perovskite-like subcell has dimensions A = a/√2 = 4.151 Å and C = c = 5.494 Å and the formula PbCu1/2(OH)2Cl or AB1/2O3. Cu(II) is coordinated by a square pyramid of 4 OH + 1 Cl and Pb(II) by a distorted square antiprism of 4 OH + 4 Cl. Structural distortions are interpreted in terms of Pb–Cu repulsions and the second-order Jahn-Teller effect.

About the article

Published Online: 2010-07-28

Published in Print: 1971-08-01


Citation Information: Zeitschrift für Kristallographie - Crystalline Materials, ISSN (Online) 2196-7105, ISSN (Print) 2194-4946, DOI: https://doi.org/10.1524/zkri.1971.134.1-2.69.

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