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Zeitschrift für Kristallographie - Crystalline Materials

Editor-in-Chief: Pöttgen, Rainer

Ed. by Antipov, Evgeny / Bismayer, Ulrich / Boldyreva, Elena V. / Huppertz, Hubert / Petrícek, Václav / Tiekink, E. R. T.

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Volume 220, Issue 8 (Aug 2005)


Phase transitions in BaTiO3: a high-pressure neutron diffraction study

Stuart A. Hayward / Simon A. T. Redfern / Howard J. Stone / Matthew G. Tucker / Karl R. Whittle / William G. Marshall
Published Online: 2009-09-25 | DOI: https://doi.org/10.1524/zkri.220.8.735.67077


The sequence of ferroelectric phase transitions (PmmP4mmAmm2) in BaTiO3 has been studied as a function of temperature (298 K–130 K) at a fixed pressure (3.2 GPa). The same sequence of transitions is observed as for ambient pressures, but the transition temperatures are reduced. The spontaneous strains of the non-cubic phases are determined. Whilst the structure of the tetragonal phase at high pressure is qualitatively similar to the ambient structure, both the spontaneous strain and the Ti displacement are smaller in the high pressure structure than the ambient structure.

About the article

Received: June 7, 2004

Accepted: October 27, 2004

Published Online: 2009-09-25

Published in Print: 2005-08-01

Citation Information: Zeitschrift für Kristallographie - Crystalline Materials, ISSN (Online) 2196-7105, ISSN (Print) 2194-4946, DOI: https://doi.org/10.1524/zkri.220.8.735.67077. Export Citation

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