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Zeitschrift für Kristallographie - Crystalline Materials

Editor-in-Chief: Pöttgen, Rainer

Ed. by Antipov, Evgeny / Boldyreva, Elena V. / Friese, Karen / Huppertz, Hubert / Jahn, Sandro / Tiekink, E. R. T.

IMPACT FACTOR 2018: 1.090
5-year IMPACT FACTOR: 2.159

CiteScore 2018: 1.47

SCImago Journal Rank (SJR) 2018: 0.892
Source Normalized Impact per Paper (SNIP) 2018: 0.722

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Temperature-dependent X-ray and neutron diffraction study of BiB3O6

Wolf-Dieter Stein / Alain Cousson / Petra Becker / Ladislav Bohatý / Markus Braden
Published Online: 2009-09-25 | DOI: https://doi.org/10.1524/zkri.2007.222.12.680

The structure of bismuth triborate has been analyzed by the combination of neutron and X-ray diffraction on powder and on single-crystalline samples. Bismuth triborate exhibits a distinct anisotropic thermal expansion with the coefficient along a being negative over the wide temperature range studied, 20 to 800 K. The remarkable crystal structure of bismuth triborate with a netlike linkage of rigid borate units [BO3] and [BO4], is found to generate the uncommon thermal expansion behavior. Our investigations gave no evidence for a structural phase transition in bismuth triborate between 3.5 and 999 K at ambient pressure.

Keywords: Bismuth triborate; Non-linear optics; Neutron diffraction; X-ray diffraction; Single crystal structure analysis; Powder diffraction structure analysis

About the article

Received: 2007-04-19

Accepted: 2007-07-30

Published Online: 2009-09-25

Published in Print: 2007-12-01

Citation Information: Zeitschrift für Kristallographie - Crystalline Materials, Volume 222, Issue 12/2007, Pages 680–689, ISSN (Online) 2196-7105, ISSN (Print) 2194-4946, DOI: https://doi.org/10.1524/zkri.2007.222.12.680.

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