Zeitschrift für Kristallographie - Crystalline Materials
Editor-in-Chief: Pöttgen, Rainer
Ed. by Antipov, Evgeny / Bismayer, Ulrich / Boldyreva, Elena V. / Huppertz, Hubert / Petrícek, Václav / Tiekink, E. R. T.
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Coexistence of hydrogen and polyanions in multinary main group element hydrides
Citation Information: Zeitschrift für Kristallographie International journal for structural, physical, and chemical aspects of crystalline materials. Volume 223, Issue 10, Pages 628–635, ISSN (Print) 0044-2968, DOI: 10.1524/zkri.2008.1016, September 2009
- Published Online:
Multinary hydrides based on mixtures of s- and p-block metals are often not fully hydrogenated, but possess a polymeric anion which is formed by the p-block component upon reduction by the s-block metals. Hydrogen may occur hydridic and exclusively coordinated by s-block metal ions (Zintl phase hydrides), or be incorporated in the polymeric anion where it acts as a covalently bonded terminating ligand (polyanionic hydrides). The current state of Zintl phase hydrides and polyanionic hydrides is reviewed with an emphasis on crystal structures and bonding principles.
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