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Zeitschrift für Kristallographie - Crystalline Materials

Editor-in-Chief: Pöttgen, Rainer

Ed. by Antipov, Evgeny / Bismayer, Ulrich / Boldyreva, Elena V. / Huppertz, Hubert / Petrícek, Václav / Tiekink, E. R. T.

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IMPACT FACTOR 2016: 3.179

CiteScore 2016: 3.30

SCImago Journal Rank (SJR) 2016: 1.097
Source Normalized Impact per Paper (SNIP) 2016: 2.592

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2196-7105
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Volume 223, Issue 10 (Oct 2008)

Issues

Light metal borohydrides: crystal structures and beyond

Yaroslav Filinchuk / Dmitry Chernyshov / Vladimir Dmitriev
Published Online: 2009-09-25 | DOI: https://doi.org/10.1524/zkri.2008.1021

Abstract

Experimental structures of M(BH4)n, where M is a 2nd–4th period element, are reviewed with a particluar emphasize on crystal chemistry. It is shown that except certain cases, the BH4 group has a nearly ideal tetrahedral geometry. Correction of the experimentally determined H-positions allows to compare directly the results obtained by different diffraction techniques and by theoretical calculations. Analysis of coordination geometries for M and BH4, and of mechanisms of phase transitions in LiBH4, suggest that the directional BH4 … M interaction is at the origin of structural complexity of borohydrides. The ways to influence their stability by chemical modification are discussed. Study of structural evolution with temperature and pressure is shown to be the way to access fundamental information on structural stability of these systems.

Keywords: Borohydrides; Structure; Polymorphism; Stability; Synchrotron diffraction

About the article

* Correspondence address: 38043 Grenoble, FRANCE,


Published Online: 2009-09-25

Published in Print: 2008-10-01


Citation Information: Zeitschrift für Kristallographie International journal for structural, physical, and chemical aspects of crystalline materials, ISSN (Print) 0044-2968, DOI: https://doi.org/10.1524/zkri.2008.1021.

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