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Zeitschrift für Kristallographie - Crystalline Materials

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Compounds of glycine with halogen or metal halogenides: review and comparison

Michel Fleck
Published Online: 2009-09-25 | DOI: https://doi.org/10.1524/zkri.2008.0020

Abstract

The large family of glycine halogenides and metal halogenides encompasses a high variety of different crystal structures. The role of the glycine molecule as a structural unit as a mono-, bi- or tridentate ligand, of the halogenide ions as well as the composition and condensation of the cationic polyhedra is discussed. With respect to the connectivity of the building units, five different structure families of glycine halogenides and glycine-metal halogenides can be distinguished. Parameters such as symmetry, ionic radii, electronegativity of cation and anion and their difference, charge, coordination number, hydration states, stoichiometric ratios and connectivity were weighed against each other in order to see if any correlations exist. The data suggest that cations with high electronegativities seem to promote formation of structures with a low grade of connectivity, i.e., isolated units, and vice versa.

Keywords: Glycine; Metal halogenids; Crystal structure; Comparison; Connectivity

About the article

Received: 2007-04-03

Accepted: 2007-12-31

Published Online: 2009-09-25

Published in Print: 2008-03-01



Citation Information: Zeitschrift für Kristallographie, ISSN (Print) 0044-2968, DOI: https://doi.org/10.1524/zkri.2008.0020. Export Citation

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A. K. Mishra, Chitra Murli, Ashok K. Verma, Yang Song, M. R. Suresh Kumar, and Surinder M. Sharma
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[2]
T. Balakrishnan, K. Ramamurthi, J. Jeyakanthan, and S. Thamotharan
Acta Crystallographica Section E Structure Reports Online, 2013, Volume 69, Number 1, Page m60
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SUBRAMANIAN NATARAJAN, BIKSHANDARKOIL R SRINIVASAN, J KALYANA SUNDAR, K RAVIKUMAR, R V KRISHNAKUMAR, and J SURESH
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[4]
K. Moovendaran, Bikshandarkoil R. Srinivasan, J. Kalyana Sundar, S.A. Martin Britto Dhas, and S. Natarajan
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[5]
Matthew R. Hudson, Damian G. Allis, Wayne Ouellette, Patrick M. Hakey, and Bruce S. Hudson
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[6]
P.V. Dhanaraj, T. Suthan, and N.P. Rajesh
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[7]
B. Raju, A. Saritha, Mukesh M. Jotani, P.S.R. Prasad, and K.A. Hussain
Physica B: Condensed Matter, 2012, Volume 407, Number 1, Page 188
[8]
Michel Fleck, Peter Held, Karolina Schwendtner, and Ladislav Bohatý
Zeitschrift für Kristallographie, 2008, Volume 223, Number 3/2008
[9]
A. A. Udovenko, N. V. Makarenko, R. L. Davidovich, L. A. Zemnikhova, and E. V. Kovaleva
Journal of Structural Chemistry, 2010, Volume 51, Number 5, Page 904
[10]
M. Fleck, R. Emmerich, and L. Bohatý
Crystal Research and Technology, 2010, Volume 45, Number 8, Page 883

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