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Zeitschrift für Kristallographie - Crystalline Materials

Editor-in-Chief: Pöttgen, Rainer

Ed. by Antipov, Evgeny / Bismayer, Ulrich / Boldyreva, Elena V. / Huppertz, Hubert / Petrícek, Václav / Tiekink, E. R. T.

12 Issues per year


IMPACT FACTOR 2016: 3.179

CiteScore 2016: 3.30

SCImago Journal Rank (SJR) 2016: 1.097
Source Normalized Impact per Paper (SNIP) 2016: 2.592

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2196-7105
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Volume 226, Issue 7 (Jul 2011)

Issues

Isostructural phase transition in the spin crossover compound [Fe(dpp)2(NCS)2] · py

Joachim Kusz / Maciej Zubko / Andy Fitch / Philipp Gütlich
  • 3 Johannes-Gutenberg-Universität Mainz, Institut für Anorganische Chemie und Analytische C, Deutschland
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Published Online: 2011-04-08 | DOI: https://doi.org/10.1524/zkri.2011.1377

Abstract

The spin crossover complex [Fe(dpp)2(NCS)2] · py crystallises in the monoclinic P2/n space group with one guest pyridine molecule per iron complex and undergoes an isostructural phase transition near 100 K on cooling and around 155 K on heating. The space group does not change upon spin transition despite the occurrence of hysteresis with ca. 55 K width, which is clearly seen in the temperature dependence of the lattice parameters. These are highly anisotropic upon spin transition, and surprisingly the unit cell volume reduces only little (0.1%) upon spin transition from high spin to low spin phase. The differences between the high- and low-spin structures are discussed.

Keywords: Spin Crossover Complex; Isostructural Phase Transition; Fe(II)

About the article

* Correspondence address: University of Silesia, Institute of Physics, ul. Bankowa 12, 40-007 Katowice, Polen,


Published Online: 2011-04-08

Published in Print: 2011-07-01


Citation Information: Zeitschrift für Kristallographie Crystalline Materials, ISSN (Print) 0044-2968, DOI: https://doi.org/10.1524/zkri.2011.1377.

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