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Zeitschrift für Kristallographie - Crystalline Materials

Editor-in-Chief: Pöttgen, Rainer

Ed. by Antipov, Evgeny / Boldyreva, Elena V. / Friese, Karen / Huppertz, Hubert / Jahn, Sandro / Tiekink, E. R. T.

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Volume 227, Issue 9

Issues

Synthesis and crystal structure of cyano-bridged three dimensional polyheteronuclear complex

Dursun Karaağaç
  • 1 Eskişehir Osmangazi University, Faculty of Arts and Sciences, Department of Physic, Eskişehir, Türkei
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Günes Süheyla Kürkçüoğlu / Okan Zafer Yeşilel / Tuncer Hokelek
  • 3 IIIHacettepe University, Faculty of Engineering, Department of Physics, Beytepe Ankara, Türkei
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Hakan Dal
Published Online: 2012-07-02 | DOI: https://doi.org/10.1524/zkri.2012.1526

Abstract

The cyano-bridged 3D heteronuclear polymeric complex, [Cd(NH3)(μ-ampy)Ni(μ-CN)4]n, (1) (ampy = 3-aminomethylpyridine), has been synthesized and characterized by FT-IR and Raman spectral, thermal and elemental analyses. The crystal structure of 1 has been determined by X-ray single crystal diffraction. The complex crystallizes in orthorhombic system with space group Pnma. In 1, Ni(II) ion is five coordinated with square-pyramidal geometry defined by the four C atoms from the four symmetry related cyano ligands and one N atom from the ampy ligand. The Cd(II) ion adopts slightly distorted octahedral coordination geometry completed by the six N atoms from one ammine, one ampy and four cyano ligands. The [Ni(CN)4]2– anion is coordinated to the adjacent four Cd(II) ions to generate a Cd—Ni(CN)4 2D undulate layer. The adjacent 2D layers are connected by the μ-ampy bridging ligands to form a 3D pillar-layered framework.

Keywords: Tetracyanonickelate(II); 3-Aminomethylpyridine; Cyano-bridged complex; Heterometallic complex; Coordination polymer

About the article

* Correspondence address: Eskisehir Osmangazi University, Faculty of Arts and Sciences, Department of Physics, 26480 Eskisehir, Türkei,


Published Online: 2012-07-02

Published in Print: 2012-09-01


Citation Information: Zeitschrift für Kristallographie Crystalline Materials, Volume 227, Issue 9, Pages 639–645, ISSN (Print) 2194-4946, DOI: https://doi.org/10.1524/zkri.2012.1526.

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