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Zeitschrift für Kristallographie - Crystalline Materials

Editor-in-Chief: Pöttgen, Rainer

Ed. by Antipov, Evgeny / Boldyreva, Elena V. / Friese, Karen / Huppertz, Hubert / Jahn, Sandro / Tiekink, E. R. T.

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Volume 228, Issue 2

Issues

Two dimensional cyano-bridged heteropolynuclear complex containing Pd ···π interactions

Dursun Karaağaç / Güneş Süheyla Kürkçüoğlu / Tuncer Hökelek / Okan Zafer Yeşilel / Yasemin Süzen
Published Online: 2013-02-04 | DOI: https://doi.org/10.1524/zkri.2013.1589

Abstract

The heteronuclear complex, [Cd(NH3)2(μ-ampy)Pd(μ-CN)2(CN)2]n (1) (ampy = 4-aminomethylpyridine), was synthesized and characterized by vibrational (FT-IR and Raman) spectroscopy, elemental and thermal analyses and single crystal X-ray diffraction techniques. The complex crystallizes in the triclinic system, space group P-1. The Cd(II) ion exhibits a distorted octahedral coordination by two different N-atoms from two symmetrically equivalent ampy ligands, two ammine ligands and two bridging cyano groups, whereas the Pd(II) ion has square planar coordination and is coordinated by four cyano ligands. The tetracyanopalladate(II) anion is coordinated to the adjacent two Cd(II) ions to generate a one-dimensional chain. The adjacent 1D chains are connected by the μ-ampy bridging ligands to form a 2D network. The 2D layers are further linked by Pd···π and hydrogen bonding interactions to generate a 3D supramolecular network. The decomposition reaction takes places in the temperature range of 40–900 °C in the static air atmosphere.

Keywords: Heteronuclear complex; Tetracyanopalladate complex; 4-aminomethylpyridine complex; Structure analysis; Vibrational spectrum

About the article

* Correspondence address: Eskişehir Osmangazi University, Faculty of Arts and Sciences, Department of Physics, TR-26480 Eskişehir, Türkei,


Published Online: 2013-02-04

Published in Print: 2013-02-01


Citation Information: Zeitschrift für Kristallographie - Crystalline Materials, Volume 228, Issue 2, Pages 100–105, ISSN (Print) 2194-4946, DOI: https://doi.org/10.1524/zkri.2013.1589.

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