Jump to ContentJump to Main Navigation
Show Summary Details
More options …

Zeitschrift für Kristallographie - Crystalline Materials

Editor-in-Chief: Pöttgen, Rainer

Ed. by Antipov, Evgeny / Bismayer, Ulrich / Boldyreva, Elena V. / Friese, Karen / Huppertz, Hubert / Tiekink, E. R. T.

12 Issues per year


IMPACT FACTOR 2017: 1.263
5-year IMPACT FACTOR: 2.057

CiteScore 2017: 2.65

Online
ISSN
2196-7105
See all formats and pricing
More options …
Volume 228, Issue 7

Issues

SUMOF-5: a mesoporous metal-organic framework with the tbo topology built from the dicopper paddle-wheel cluster and a new tritopic linker

Qingxia Yao / Jie Su / Xiaodong Zou

Abstract

A mesoporous metal-organic framework Cu3(PTB)2(H2O)3 · guest (denoted as SUMOF-5) has been synthesized using a new tritopic linker pyridine-2,4,6-tribenzoic acid (H3PTB). SUMOF-5 is cubic with the space group Fm-3m and a = 47.272(3) Å. The framework is built of the dicopper paddle-wheel secondary building unit (SBU) [Cu2(OOC)4(H2O)2] and contains two different äcavities of 1.22 and 2.33 nm in diameter, respectively. The framework topology follows the (3,4)-connected tbo net, and can be regarded as an extended version of Cu3(BTC)2(H2O)3 · guest (HKUST-1, BTC = benzene tricarboxylate). The structure of SUMOF-5 is compared to other MOFs built from dicopper paddle-wheels and tritopic linkers. SUMOF-5 has permanent porosity with a Langmuir surface area of 1733 m2/g and is stable in various organic solvents, which makes this material potentially useful as a crystalline carrier for loading molecular catalysts or drugs.

This article offers supplementary material which is provided at the end of the article.

Keywords: Alcohol sorption; Coordination polymers; Crystal structure; HKUST-1; Porous materials

About the article

* Correspondence address: Stockholm University, Berzelii Center EXSELENT on Porous Materials, Dep. of Materials and Environmental Chemistry, SE-106 91 Stockholm, Schweden,


Published in Print: 2013-07-01


Citation Information: Zeitschrift für Kristallographie - Crystalline Materials, Volume 228, Issue 7, Pages 323–329, ISSN (Print) 2194-4946, DOI: https://doi.org/10.1524/zkri.2013.1629.

Export Citation

Supplementary Article Materials

Citing Articles

Here you can find all Crossref-listed publications in which this article is cited. If you would like to receive automatic email messages as soon as this article is cited in other publications, simply activate the “Citation Alert” on the top of this page.

[1]
Xueliang Mu, Yipei Chen, Edward Lester, and Tao Wu
Microporous and Mesoporous Materials, 2018
[2]
Wenlong Xu, Kedar Bahadur Thapa, Qiang Ju, Zhenlan Fang, and Wei Huang
Coordination Chemistry Reviews, 2017
[3]
Qingxia Yao, Antonio Bermejo Gómez, Jie Su, Vlad Pascanu, Yifeng Yun, Haoquan Zheng, Hong Chen, Leifeng Liu, Hani Nasser Abdelhamid, Belén Martín-Matute, and Xiaodong Zou
Chemistry of Materials, 2015, Volume 27, Number 15, Page 5332
[4]
Erika Mühlbauer, Arne Klinkebiel, Ole Beyer, Florian Auras, Stefan Wuttke, Ulrich Lüning, and Thomas Bein
Microporous and Mesoporous Materials, 2015, Volume 216, Page 51
[5]
Mian Li, Dan Li, Michael O’Keeffe, and Omar M. Yaghi
Chemical Reviews, 2014, Volume 114, Number 2, Page 1343
[6]
John Meurig Thomas and Rowan K. Leary
Angewandte Chemie International Edition, 2014, Volume 53, Number 45, Page 12020
[7]
John Meurig Thomas and Rowan K. Leary
Angewandte Chemie, 2014, Volume 126, Number 45, Page 12214

Comments (0)

Please log in or register to comment.
Log in