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Zeitschrift für Kristallographie - Crystalline Materials

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Volume 229, Issue 8

Issues

One- and two-dimensional heteropolynuclear complexes with tetracyanonickelate(II) and 2-pyridinemethanol

Elvan Sayın
  • The Institute of Science, Department of Physics, Eskişehir Osmangazi University, TR-26480 Eskişehir, Turkey
  • Other articles by this author:
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/ Güneş Süheyla Kürkçüoğlu
  • Corresponding author
  • Faculty of Arts and Sciences, Department of Physics, Eskişehir Osmangazi University, TR-26480 Eskişehir, Turkey
  • Email
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Okan Zafer Yeşilel
  • Faculty of Arts and Sciences, Department of Chemistry, Eskişehir Osmangazi University, TR-26480 Eskişehir, Turkey
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/ Tuncer Hökelek
  • Faculty of Engineering, Department of Physics, Hacettepe University, TR-06800, Beytepe Ankara, Turkey
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  • De Gruyter OnlineGoogle Scholar
/ Orhan Büyükgüngör
  • Faculty of Arts and Sciences, Department of Physics, Ondokuz Mayıs University, TR-55139 Samsun, Turkey
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Published Online: 2014-07-12 | DOI: https://doi.org/10.1515/zkri-2014-1756

Abstract

Three new cyano complexes, [Cu(hmp)2] [Cu(hmpH)2 Ni(μ-CN)2(CN)2]2·4H2 O (1), [Zn3(hmp)2(hmpH)4 Ni2(μ-CN)6(CN)2]·2H2 O (2) and [Cd2(H2 O)2(hmpH)2 Ni(μ-CN)4 Ni(μ-CN)2(CN)2] (3) (2-pyridinemethanol abbreviated to hmpH), have been synthesized and characterized by elemental analysis, vibrational spectroscopy (FT-IR and Raman), thermal and single-crystal X-ray diffraction analyses. In 1, Cu(II) ions are connected by the tetracyanonickelate(II) anions to form one-dimensional (1D) zig-zag chains. In 2, tetracyanonickelate(II) ions are coordinated to the neighboring three Zn(II) ions to form a one-dimensional double chain structure. In 3, Cd(II) ions are connected by tetrakis-monodentate tetracyanonickelate(II) ions to form a one-dimensional ladder-like chain. Adjacent ladder-like chains are linked by the bis-monodentate tetracyanonickelate(II) ions to generate a 2D network. The 3D supramolecular network of the complexes constructed by intermolecular interactions such as Ni···π, C-H···Ni, π···π and hydrogen bonding interactions.

This article offers supplementary material which is provided at the end of the article.

Keywords: cyanide complexes; 2-pyridinemethanol complexes; tetracyanonickelate(II) complexes; C-H···Ni interaction; Ni···π interaction; π···π interaction; O-H···O interaction

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About the article

Corresponding author: Güneş Süheyla Kürkçüoğlu, Faculty of Arts and Sciences, Department of Physics, Eskişehir Osmangazi University, TR-26480 Eskişehir, Turkey, Phone: +90 222 2393750; Fax: +90 222 2393578, E-mail:


Received: 2014-03-26

Accepted: 2014-06-05

Published Online: 2014-07-12

Published in Print: 2014-08-01


Citation Information: Zeitschrift für Kristallographie - Crystalline Materials, Volume 229, Issue 8, Pages 563–572, ISSN (Online) 2196-7105, ISSN (Print) 2194-4946, DOI: https://doi.org/10.1515/zkri-2014-1756.

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