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Zeitschrift für Kristallographie - Crystalline Materials

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Volume 230, Issue 6

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Synthesis, crystal structure and spectroscopic properties of one-dimensional zinc(II)–cyanide complex with 1-methylimidazole, [Zn(μ-CN)(CN)(1-meim)]n

Elvan Sayın
  • Graduate School of Natural and Applied Sciences, Physics, Eskişehir Osmangazi University, TR-26480 Eskişehir, Turkey
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Güneş Süheyla Kürkçüoğlu
  • Corresponding author
  • Faculty of Arts and Sciences, Department of Physics, Eskişehir Osmangazi University, TR-26480 Eskişehir, Turkey
  • Email
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Okan Zafer Yeşilel
  • Faculty of Arts and Sciences, Department of Chemistry, Eskişehir Osmangazi University, TR-26480 Eskişehir, Turkey
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Tuncer Hökelek
  • Faculty of Engineering, Department of Physics, Hacettepe University, TR-06800 Beytepe Ankara, Turkey
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Published Online: 2015-03-14 | DOI: https://doi.org/10.1515/zkri-2015-0001

Abstract

A new one-dimensional Zn(II)–cyanide complex with 1-methylimidazole ligand, [Zn(μ-CN)(CN)(1-meim)]n (1-meim: 1-methylimidazole) has been synthesized and characterized by spectral (FT-IR and Raman) methods, elemental analysis, thermal (TG, DTG and DTA) analysis and single crystal X-ray diffraction techniques. The complex crystallizes in the monoclinic system, P21 space group. The asymmetric unit contains one Zn(II), one 1-meim and two cyanide ligands. The coordination sphere of the Zn(II) ion exhibits a distorted tetrahedral geometry. In the crystal structure, the symmetry related zinc(II) atoms are bridged by the cyanide anions to form one dimensional chains running along the b-axis. Intermolecular C–H···N hydrogen bonds link the adjacent polynuclear chains forming two dimensional layers through the R1818(2) ring motifs, where the layers formed are oriented in parallel to (020).

This article offers supplementary material which is provided at the end of the article.

Keywords: crystal structure; cyanide complex; 1D complex; 1-methylimidazole; zinc(II) complex

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About the article

Corresponding author: Güneş Süheyla Kürkçüoğlu, Faculty of Arts and Sciences, Department of Physics, Eskişehir Osmangazi University, TR-26480 Eskişehir, Turkey, Tel.: +90 222 2393750; Fax: +90 222 2393578, E-mail:


Received: 2015-01-06

Accepted: 2015-02-15

Published Online: 2015-03-14

Published in Print: 2015-06-01


Citation Information: Zeitschrift für Kristallographie - Crystalline Materials, Volume 230, Issue 6, Pages 421–426, ISSN (Online) 2196-7105, ISSN (Print) 2194-4946, DOI: https://doi.org/10.1515/zkri-2015-0001.

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