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Zeitschrift für Kristallographie - Crystalline Materials

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Volume 230, Issue 9-10 (Sep 2015)

Issues

[NaCl][Cu(HSeO3)2], NaCl-intercalated Cu(HSeO3)2: synthesis, crystal structure and comparison with related compounds

Vadim M. Kovrugin
  • Department of Crystallography, St. Petersburg State University, Universitetskaya nab. 7/9, 199034 St. Petersburg, Russia
  • UCCS, ENSCL, Université Lille 1, CNRS, UMR 8181, 59652 Villeneuve d’Ascq, France
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Sergey V. Krivovichev
  • Corresponding author
  • Department of Crystallography, St. Petersburg State University, Universitetskaya nab. 7/9, 199034 St. Petersburg, Russia
  • Institute of Silicate Chemistry, Russian Academy of Sciences, Makarova Emb. 6, 199034 St. Petersburg, Russia
  • Email
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Olivier Mentré / Marie Colmont
Published Online: 2015-08-07 | DOI: https://doi.org/10.1515/zkri-2015-1849

Abstract

Single crystals of [NaCl][Cu(HSeO3)2] have been prepared by the chemical vapor transport reactions. Its crystal structure (monoclinic, C2/c, a = 13.9874(7), b = 7.2594(4), c = 9.0421(5) Å, β = 127.046(2)°, V = 732.81(7) Å3) is based upon electroneutral [Cu(HSeO3)2] sheets formed by corner sharing between the [CuO4] squares and (HSeO3) groups that are parallel to the (100) plane. Each (SeO2OH) group forms the Oh1...O2 hydrogen bond to an adjacent hydroselenite group to constitute a [(SeO2OH)2]2– dimer that provides additional stabilization of the copper diselenite sheet. The [Cu(HSeO3)2] sheets alternate with the sheets consisting of zigzag–Na–Cl–Na–Cl–chains formed by Cl atoms and disordered Na sites. The chains are parallel to the c axis. The linkage between the alternating electroneutral [Cu(HSeO3)2] and [NaCl] sheets is provided by the Cu–Cl and Na–O bonds. The coordination of Na is fivefold and consists of three O and two Cl atoms. [NaCl][Cu(HSeO3)2] is a new member of the group of compounds based upon the M(HSeO3)2 layers (M2+ = Cu, Co, Cd). The prototype structure for this group is [Cu(HSeO3)2] that does not have any chemical species separating the copper hydroselenite layers. In other compounds, the interlayer space between the [Cu(HSeO3)2]0 layers is occupied by structural units of different complexity. [NaCl][Cu(HSeO3)2] can be considered as [Cu(HSeO3)2] intercalated with the NaCl layers consisting of one-dimensional–Na–Cl–Na–Cl–chains.

Keywords: copper; crystal structure; intercalated structures; layered compounds; selenite

References

  • [1]

    S. Hu, M. Johnsson, Synthesis and crystal structure of two synthetic oxofluoride framework compounds – Co2TeO3F2 and Co2SeO3F2. Dalton Trans. 2012, 41, 12786.Google Scholar

  • [2]

    P. S. Berdonosov, O. Janson, A. V. Olenev, S. V. Krivovichev, H. Rosner, V. A. Dolgikh, A. A. Tsirlin, Crystal structures and variable magnetism of PbCu2(XO3)2Cl2 with X = Se, Te. Dalton Trans. 2013, 42, 9547.Web of ScienceGoogle Scholar

  • [3]

    Y. H. Kim, D. W. Lee, K. M. Ok, α-ScVSe2O8, β-ScVSe2O8, and ScVTe2O8: new quaternary mixed metal oxides composed of only second-order Jahn-Teller distortive cations. Inorg. Chem. 2013, 52, 11450.Web of ScienceCrossrefGoogle Scholar

  • [4]

    Y. Shin, D. W. Lee, K. Y. Choi, H.-J. Koo, K. M. Ok, VSb(SeO3)4, first selenite containing V3+ cation: synthesis, structure, characterization, magnetic properties, and calculations. Inorg. Chem. 2013, 52, 14224.CrossrefGoogle Scholar

  • [5]

    Y. H. Kim, D. W. Lee, K. M. Ok, Noncentrosymmetric YVSe2O8 and centrosymmetric YVTe2O8: macroscopic centricities influenced by the size of lone pair cation linkers. Inorg. Chem. 2014, 53, 1250.Web of ScienceCrossrefGoogle Scholar

  • [6]

    T. Eaton, J. Lin, J. N. Cross, J. T. Stritzinger, T. E. Albrecht-Schmitt, Th(VO3)2(SeO3) and Ln(VO3)2(IO3) (Ln = Ce, Pr, Nd, Sm, and Eu): unusual cases of aliovalent substitution. Chem. Comm. 2014, 50, 3668.CrossrefGoogle Scholar

  • [7]

    S. Hu, M. Johnsson, J. M. Law, J. L. Bettis, M.-H. Whangbo, R. K. Kremer, Crystal structure and magnetic properties of FeSeO3F – alternating antiferromagnetic S = 5/2 chains. Inorg. Chem. 2014, 53, 4250.CrossrefGoogle Scholar

  • [8]

    X.-L. Cao, F. Kong, C.-L. Hu, X. Xu, J.-G. Mao, Pb4V6O16(SeO3)3(H2O), Pb2VO2(SeO3)2Cl, and PbVO2(SeO3)F: new lead(II)-vanadium(V) mixed-metal selenites featuring novel anionic skeletons. Inorg. Chem. 2014, 53, 8816.Web of ScienceCrossrefGoogle Scholar

  • [9]

    K. L. Kilminster, F. J. Lincoln, B. W. Skelton, A. H. White, A barium vanadium(V) selenite hydrate, Ba(VO2)2(SeO3)2·H2O: a novel 3D polymer of cross-linked sheets with embedded …V-O-V… 21 helices. Austr. J. Chem. 2014, 67, 1878.Web of ScienceGoogle Scholar

  • [10]

    J. H. Koffer, J. H. Olshansky, M. D. Smith, K. J. Hernandez, M. Zeller, G. M. Ferrence, J. Schrier, A. J. Norquist, Formation principles for templated vanadium selenite oxalates. Cryst. Growth Des. 2013, 13, 4504.Web of ScienceCrossrefGoogle Scholar

  • [11]

    A. Aliev, V. M. Kovrugin, M. Colmont, C. Terryn, M. Huve, O. I. Siidra, S. V. Krivovichev, O. Mentre, Revised bismuth chloroselenite system: evidence of a noncentrosymmmetric structure with a giant unit cell. Cryst. Growth Des. 2014, 14, 3026.Web of ScienceCrossrefGoogle Scholar

  • [12]

    J. H. Olshansky, K. J. Wiener, M. D. Smith, A. Nourmahnad, M. J. Charles, M. Zeller, J. Schrier, A. J. Norquist, Formation principles for vanadium selenites: the role of pH on product composition. Inorg. Chem. 2014, 53, 12027.CrossrefWeb of ScienceGoogle Scholar

  • [13]

    M. Gemmi, I. Campostrini, F. Demartin, T. E. Gorelik, C. M. Gramaccioli, Structure of the new mineral sarrabusite, Pb5CuCl4(SeO3)4, solved by manual electron-diffraction tomography. Acta Crystallogr. 2012, B68, 15.Web of ScienceCrossrefGoogle Scholar

  • [14]

    S. V. Krivovichev, S. K. Filatov, L. P. Vergasova, The crystal structure of ilinskite, NaCu5O2(SeO3)2Cl3, and review of mixed-ligand CuOmCln coordination geometries in minerals and inorganic compounds. Mineral. Petrol. 2013, 107, 235.Web of ScienceCrossrefGoogle Scholar

  • [15]

    R. R. Shuvalov, L. P. Vergasova, T. F. Semenova, S. K. Filatov, S. V. Krivovichev, O. I. Siidra, N. S. Rudashevsky, Prewittite, KPb1.5Cu6Zn(SeO3)2O2Cl10, a new mineral from Tolbachik Fumaroles, Kamchatka Peninsula, Russia: description and crystal structure. Amer. Mineral. 2013, 98, 463.CrossrefGoogle Scholar

  • [16]

    S. J. Mills, A. R. Kampf, A. G. Christy, R. M. Housley, B. Thorne, Y.-S. Chen, I. M. Steele, Favreauite, a new selenite mineral from the El Dragon mine, Bolivia. Eur. J. Mineral. 2014, 26, 771.Web of ScienceGoogle Scholar

  • [17]

    L. P. Vergasova, T. F. Semenova, S. V. Krivovichev, S. K. Filatov, A. A. Zolotarev, Jr., V. V. Ananiev, Nicksobolevite, Cu7(SeO3)2O2Cl6, a new complex copper oxoselenite chloride from Tolbachik fumaroles, Kamchatka peninsula, Russia. Eur. J. Mineral. 2014, 26, 439.Web of ScienceCrossrefGoogle Scholar

  • [18]

    Z. Mayerová, M. Johnsson, S. Lidin, Lone-pair interfaces that divide inorganic materials into ionic and covalent parts. Angew. Chem. Int. Ed. 2006, 45, 5602.CrossrefGoogle Scholar

  • [19]

    V. Jo, M. K. Kim, D. W. Lee, I. W. Shim, K. M. Ok, Lone pairs as chemical scissors in new antimony oxychlorides, Sb2ZnO3Cl2 and Sb16Cd8O25Cl14. Inorg. Chem. 2010, 49, 2990.Web of ScienceGoogle Scholar

  • [20]

    S. Hu, M. Johnsson, Synthesis and crystal structure of Fe6Ca2(SeO3)9Cl4 – a porous oxohalide. Dalton Trans. 2013, 42, 7859.Google Scholar

  • [21]

    I. Zimmermann, M. Johnsson, A synthetic route toward layered materials: introducing stereochemically active lone-pairs into transition metal oxohalides. Cryst. Growth Des. 2014, 14, 5252.Web of ScienceCrossrefGoogle Scholar

  • [22]

    I. Zimmermann, A. Corgnet, M. Johnsson, S. Lidin, Synthesis and crystal structure of a series of incommensurately modulated composite oxohalide compounds. Dalton Trans. 2014, 43, 15812.Google Scholar

  • [23]

    H. Effenberger, Cu(SeO2OH)2: synthesis and crystal structure. Z. Kristallogr. 1985, 173, 267.Google Scholar

  • [24]

    L. Hiltunen, M. Leskela, L. Niinisto, M. Tammenmaa, Crystal structure of copper hydrogenselenite monohydrate. Acta Chem. Scand. 1985, A39, 809.CrossrefGoogle Scholar

  • [25]

    A. M. Lafront, J. C. Trombe, ‘Layered hydrogenselenites’. I. Synthesis, structure redetermination of Cu(HSeO3)2(H2O)2 and determination of (Cu(HSeO3)2(NO3)2)2–.2(NH4)+, NH4NO3. Structural relationships of these complexes with (Cu(HSeO3)2). Inorg. Chim. Acta 1995, 234, 19.Google Scholar

  • [26]

    A. M. Lafront, J. C. Trombe, J. Bonvoisin, ‘Layered hydrogenselenites’. II. Synthesis, structure studies and magnetic properties of a novel series of bimetallic hydrogenselenites: Cu(HSeO3)2MCl2(H2O)4, M(II) = Mn, Co, Ni, Cu, Zn. Inorg. Chim. Acta 1995, 238, 15.Google Scholar

  • [27]

    J. C. Trombe, A. M. Lafront, J. Bonvoisin, Synthesis, structure and magnetic measurement of a new layered copper hydrogenselenite: (Cu(HSeO3)2).((NH4)Cl). Inorg. Chim. Acta 1997, 262, 47.Google Scholar

  • [28]

    W. T. A. Harrison, M. G. Johnston, Syntheses and structures of two selenite chloride hydrates: Co(HSeO3)Cl.3(H2O) and Cu(HSeO3)Cl.2(H2O). Z. Anorg. Allg. Chem. 2000, 626, 2487.Google Scholar

  • [29]

    M. G. Johnston, W. T. A. Harrison, Cobalt hydrogen selenite chloride dihydrate, Co(HSeO3)Cl.2(H2O). Acta Crystallogr. 2003, E59, i62.Google Scholar

  • [30]

    V. M. Kovrugin, M. Colmont, O. Mentré, O. I. Siidra, S. V. Krivovichev, Dimers of oxocentered [OCu4]6+ tetrahedra in two novel copper selenite chlorides, K[Cu3O](SeO3)2Cl and Na2[Cu7O2](SeO3)4Cl4, and related minerals and inorganic compounds. Mineral. Mag. 2015, in press.Google Scholar

  • [31]

    G. M. Sheldrick, A short history of SHELX. Acta Crystallogr. 2008, A64, 112.CrossrefWeb of ScienceGoogle Scholar

  • [32]

    J. B. Parise, B. G. Hyde, The structure of atacamite and its relationships to spinel. Acta Crystallogr. 1986, B42, 1277.Google Scholar

  • [33]

    O. I. Siidra, S. V. Krivoivchev, T. Armbruster, S. K. Filatov, I. V. Pekov, The crystal structure of leningradite, PbCu3(VO4)2Cl2. Can. Mineral. 2007, 45, 445.Google Scholar

About the article

Corresponding author: Sergey V. Krivovichev, Department of Crystallography, St. Petersburg State University, Universitetskaya nab. 7/9, 199034 St. Petersburg, Russia; and Institute of Silicate Chemistry, Russian Academy of Sciences, Makarova Emb. 6, 199034 St. Petersburg, Russia, E-mail:


Received: 2015-03-02

Accepted: 2015-05-29

Published Online: 2015-08-07

Published in Print: 2015-09-01


Citation Information: Zeitschrift für Kristallographie - Crystalline Materials, ISSN (Online) 2196-7105, ISSN (Print) 2194-4946, DOI: https://doi.org/10.1515/zkri-2015-1849.

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