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Zeitschrift für Kristallographie - Crystalline Materials

Editor-in-Chief: Pöttgen, Rainer

Ed. by Antipov, Evgeny / Bismayer, Ulrich / Boldyreva, Elena V. / Huppertz, Hubert / Petrícek, Václav / Tiekink, E. R. T.

12 Issues per year


IMPACT FACTOR increased in 2015: 2.560
Rank 8 out of 26 in category Cristallography in the 2015 Thomson Reuters Journal Citation Report/Science Edition

SCImago Journal Rank (SJR) 2015: 0.827
Source Normalized Impact per Paper (SNIP) 2015: 1.198
Impact per Publication (IPP) 2015: 1.834

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2196-7105
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Divalent metal phosphonates – new aspects for syntheses, in situ characterization and structure solution

Manuel Wilke
  • BAM Federal Institute for Materials Research and Testing Richard-Willstätter-Straße 11, 12489 Berlin, Germany
  • Department of Chemistry, Humboldt-Universität zu Berlin, Brook-Taylor-Str. 2, 12489 Berlin, Germany
/ Sven Bach
  • Institut für Anorganische Chemie und Analytische Chemie, Johannes Gutenberg-Universität, Duesbergweg 10-14, D-55099 Mainz, Germany
/ Tatiana E. Gorelik
  • Institut für Anorganische Chemie und Analytische Chemie, Johannes Gutenberg-Universität, Duesbergweg 10-14, D-55099 Mainz, Germany
/ Ute Kolb
  • Institut für Anorganische Chemie und Analytische Chemie, Johannes Gutenberg-Universität, Duesbergweg 10-14, D-55099 Mainz, Germany
/ Wolfgang Tremel
  • Institut für Anorganische Chemie und Analytische Chemie, Johannes Gutenberg-Universität, Duesbergweg 10-14, D-55099 Mainz, Germany
/ Franziska Emmerling
  • BAM Federal Institute for Materials Research and Testing Richard-Willstätter-Straße 11, 12489 Berlin, Germany
  • :
Published Online: 2016-10-18 | DOI: https://doi.org/10.1515/zkri-2016-1971

Abstract

Divalent metal phosphonates are promising hybrid materials with a broad field of application. The rich coordination chemistry of the phosphonate linkers enables the formation of structures with different dimensionalities ranging from isolated complexes and layered structures to porous frameworks incorporating various functionalities through the choice of the building blocks. In brief, metal phosphonates offer an interesting opportunity for the design of multifunctional materials. Here, we provide a short review on the class of divalent metal phosphonates discussing their syntheses, structures, and applications. We present the advantages of the recently introduced mechanochemical pathway for the synthesis of divalent phosphonates as a possibility to generate new, in certain cases metastable compounds. The benefits of in situ investigation of synthesis mechanisms as well as the implementation of sophisticated methods for the structure analysis of the resulting compounds are discussed.

Keywords: ADT; mechanochemistry; phosphonates


Received: 2016-06-08

Accepted: 2016-09-13

Published Online: 2016-10-18

Published in Print: 2017-02-01


Citation Information: Zeitschrift für Kristallographie - Crystalline Materials. Volume 232, Issue 1-3, Pages 209–222, ISSN (Online) 2196-7105, ISSN (Print) 2194-4946, DOI: https://doi.org/10.1515/zkri-2016-1971, October 2016

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