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Zeitschrift für Kristallographie - Crystalline Materials

Editor-in-Chief: Pöttgen, Rainer

Ed. by Antipov, Evgeny / Boldyreva, Elena V. / Friese, Karen / Huppertz, Hubert / Jahn, Sandro / Tiekink, E. R. T.


IMPACT FACTOR 2018: 1.090
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2196-7105
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Volume 234, Issue 5

Issues

Na3Sm(PO4)2: (3+1)-dimensional commensurately modulated structure model and photoluminescence properties

Rui-Juan Zhang
  • College of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo, Henan 454000, China
  • Other articles by this author:
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/ Dan Zhao
  • Corresponding author
  • College of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo, Henan 454000, China
  • Email
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Qiu Zhong
  • Henan Key Laboratory of Coal Green Conversion, Henan Polytechnic University, Jiaozuo, Henan Province 454000, China
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/ Ya-Li Xue
  • College of Chemistry and Chemical Engineering, Henan Polytechnic University, Jiaozuo, Henan 454000, China
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ Guang-Xu Huang
  • Corresponding author
  • Henan Key Laboratory of Coal Green Conversion, Henan Polytechnic University, Jiaozuo, Henan Province 454000, China
  • Email
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2018-12-04 | DOI: https://doi.org/10.1515/zkri-2018-2095

Abstract

For the first time, we determined the detailed crystal structure of Na3Sm(PO4)2 using single crystal X-ray diffraction and established the commensurately modulated structure model using the superspace formalism. The structure adopts a (3+1)-dimensional superspace group Pca21(0β0)000 with the modulation vector q=1/3b*. At the same time, the photoluminescent properties of Na3Sm(PO4)2 sintered at different temperatures between 800 and 1200°C were studied. Under near-UV excitation (402 nm), Na3Sm(PO4)2 shows intense characteristic emission bands of Sm3+ (561, 596, 642 nm) with the CIE coordinate of (0.5709, 0.4282), corresponding to orange color. The excitation spectrum covers a wide range from 350 nm to 470 nm, which indicates that Na3Sm(PO4)2 can be efficiently activated by near-UV or visuable LED ship.

This article offers supplementary material which is provided at the end of the article.

Keywords: commensurate modulation; crystal structure; luminescent properties; phosphate; X-ray diffraction

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About the article

Received: 2018-05-21

Accepted: 2018-11-17

Published Online: 2018-12-04

Published in Print: 2019-05-27


Citation Information: Zeitschrift für Kristallographie - Crystalline Materials, Volume 234, Issue 5, Pages 281–289, ISSN (Online) 2196-7105, ISSN (Print) 2194-4946, DOI: https://doi.org/10.1515/zkri-2018-2095.

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