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Zeitschrift für Kristallographie - Crystalline Materials

Editor-in-Chief: Pöttgen, Rainer

Ed. by Antipov, Evgeny / Boldyreva, Elena V. / Friese, Karen / Huppertz, Hubert / Jahn, Sandro / Tiekink, E. R. T.


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2196-7105
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Volume 234, Issue 5

Issues

A new structural motif for cadmium dithiocarbamates: crystal structures and Hirshfeld surface analyses of homoleptic zinc and cadmium morpholine dithiocarbamates

Jimmy Ahmad
  • Department of Chemistry, Kulliyyah of Science, International Islamic University Malaysia (IIUM), Jalan Sultan Ahmad Shah, 25200 Bandar Indera Mahkota, Kuantan, Pahang, Malaysia
  • Other articles by this author:
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/ Fiona N.-F. How
  • Department of Chemistry, Kulliyyah of Science, International Islamic University Malaysia (IIUM), Jalan Sultan Ahmad Shah, 25200 Bandar Indera Mahkota, Kuantan, Pahang, Malaysia
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/ Siti Nadiah Abdul Halim / Mukesh M. Jotani
  • Department of Physics, Bhavan’s Sheth R. A. College of Science, Ahmedabad, Gujarat 380001, India
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/ See Mun Lee
  • Research Centre for Crystalline Materials, School of Science and Technology, Sunway University, 47500 Bandar Sunway, Selangor Darul Ehsan, Malaysia
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/ Edward R.T. Tiekink
  • Corresponding author
  • Research Centre for Crystalline Materials, School of Science and Technology, Sunway University, 47500 Bandar Sunway, Selangor Darul Ehsan, Malaysia
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Published Online: 2018-12-11 | DOI: https://doi.org/10.1515/zkri-2018-2141

Abstract

The crystal and molecular structures of two homoleptic morpholine-derived dithiocarbamates of zinc, binuclear {Zn[S2CN(CH2CH2)2O)2]2}2 (1), and cadmium, one-dimensional coordination polymer {Cd[S2CN(CH2CH2)2O)2]2}2 (2), are described. In 1, a centrosymmetric binuclear molecule is found as there are equal numbers of chelating and bidentate bridging dithiocarbamate ligands; weak transannular Zn···S interactions are found within the resultant eight-membered {···SCSZn}2 ring which has the form of a chair. The resultant 4+1 S5 donor set is highly distorted with the geometry tending towards a square-pyramid. By contrast, a square-planar geometry is found in centrosymmetric 2 defined by symmetrically chelating dithiocarbamate ligands. The presence of Cd···S secondary bonding in the crystal of 2 leads to a distorted 4+2 S6 octahedron and a linear coordination polymer, which is unprecedented in the structural chemistry of cadmium dithiocarbamates. The analyses of the Hirshfeld surfaces for 1 and 2 show the dominance of H···H, S···H/H···S and O···H/H···O contacts to the surface, i.e. contributing around 90 and 80%, respectively.

This article offers supplementary material which is provided at the end of the article.

Keywords: cadmium; coordination polymer; crystal structure analysis; dithiocarbamate; Hirshfeld surface; X-ray diffraction; zinc

References

  • [1]

    E. R. T. Tiekink, Crystals2018, 8, 18.CrossrefGoogle Scholar

  • [2]

    E. R. T. Tiekink, Crystals2018, 8, 292.CrossrefGoogle Scholar

  • [3]

    S. N. A. Halim, Personal communication to the Cambridge Structural Database, 2015. Refcode: QUQTED.Google Scholar

  • [4]

    W. Clegg, R. A. Coxall, Personal communication to the Cambridge Structural Database, 2016. Refcode: OJEQUR.Google Scholar

  • [5]

    A. C. Mafud, Acta Crystallogr. E2012, 66, m1025.Google Scholar

  • [6]

    CrysAlis PRO, Rigaku Oxford Diffraction, Yarnton, Oxfordshire, England, 2014.Google Scholar

  • [7]

    G. M. Sheldrick, Acta Crystallogr. A2008, 64, 112.Google Scholar

  • [8]

    G. M. Sheldrick, Acta Crystallogr. C2015, 71, 3.Google Scholar

  • [9]

    L. J. Farrugia, J. Appl. Crystallogr. 2012, 45, 849.CrossrefGoogle Scholar

  • [10]

    A. L. Spek, J. Appl. Crystallogr. 2003, 36, 7.CrossrefGoogle Scholar

  • [11]

    K. Brandenburg, DIAMOND. Crystal Impact GbR, Bonn, Germany, 2006.Google Scholar

  • [12]

    A. Bondi, J. Phys. Chem. 1964, 68, 441.CrossrefGoogle Scholar

  • [13]

    A. W. Addison, T. N. Rao, J. Reedijk, J. van Rijn, G. C. Verschoor, J. Chem. Soc. Dalton Trans. 1984, 1349.Google Scholar

  • [14]

    N. W. Alcock, Adv. Inorg. Chem. Radiochem. 1972, 15, 1.CrossrefGoogle Scholar

  • [15]

    I. Haiduc, Secondary Bonding in J. L. Atwood, J. Steed, (Eds), Encyclopedia of Supramolecular Chemistry, Marcel Dekker Inc., New York, pp. 1215, 2004.Google Scholar

  • [16]

    E. R. T. Tiekink, Coord. Chem. Rev. 2017, 345, 209.CrossrefGoogle Scholar

  • [17]

    M. J. Cox, E. R. T. Tiekink, Z. Kristallogr. 1999, 214, 184.Google Scholar

  • [18]

    Y. Bing, X. Li, M. Zha, Y. Lu, Acta Crystallogr. E2010, 66, m1500.CrossrefGoogle Scholar

  • [19]

    Y. S. Tan, A. L. Sudlow, K. C. Molloy, Y. Morishima, K. Fujisawa, W. J. Jackson, W. Henderson, S. N. Bt. A. Halim, S. W. Ng, E. R. T. Tiekink, Cryst. Growth Des.2013, 13, 3046.CrossrefGoogle Scholar

  • [20]

    Y. S. Tan, S. N. A. Halim, E. R. T. Tiekink, Z. Kristallogr. – Cryst. Mat. 2016, 231, 113.Google Scholar

  • [21]

    V. G. Jr. Young, E. R. T. Tiekink, Acta Crystallogr. E2002, 58, m537.CrossrefGoogle Scholar

  • [22]

    B. F. Abrahams, B. F. Hoskins, E. R. T. Tiekink, G. Winter, Aust. J. Chem. 1988, 41, 1117.CrossrefGoogle Scholar

  • [23]

    J. J. McKinnon, M. A. Spackman, A. S. Mitchell, Acta Crystallogr. B2004, 60, 627.CrossrefGoogle Scholar

  • [24]

    M. J. Turner, J. J. McKinnon, S. K. Wolff, D. J. Grimwood, P. R. Spackman, D. Jayatilaka, M. A. Spackman, CrystalExplorer17, University of Western Australia, The Nedlands, Western Australia, 2017.Google Scholar

  • [25]

    M. M. Jotani, J. L. Wardell, E. R. T. Tiekink, Z. Kristallogr. 2019, 234, 43.Google Scholar

  • [26]

    M. M. Jotani, P. Poplaukhin, H. D. Arman, E. R. T. Tiekink, Z. Kristallogr. – Cryst. Mat. 2017, 232, 287.Google Scholar

  • [27]

    D. Chen, C. S. Lai, E. R. T. Tiekink, Z. Kristallogr. 2003, 218, 747.Google Scholar

  • [28]

    M. K. Milčič, V. B. Medaković, D. N. Sredojević, N. O. Juranić, Z. D. Tomić, S. D. Zarić, Inorg. Chem. 2006, 45, 4755.CrossrefGoogle Scholar

  • [29]

    E. R. T. Tiekink, J. Zukerman-Schpector, Chem. Commun. 2011, 47, 6623.CrossrefGoogle Scholar

  • [30]

    M. M. Jotani, Y. S. Tan, E. R. T. Tiekink, Z. Kristallogr.2016, 231, 403.Google Scholar

  • [31]

    Y. S. Tan, S. N. A. Halim, K. C. Molloy, A. L. Sudlow, A. Otero-de-la-Roza, E. R. T. Tiekink, CrystEngComm2016, 18, 1105.CrossrefGoogle Scholar

  • [32]

    Dušan P. Malenov, Goran V. Janjić, Vesna B. Medaković, Michael B. Hall, Snežana D. Zarić, Coord. Chem. Rev. 2017, 345, 318.CrossrefGoogle Scholar

  • [33]

    M. A. Spackman, J. J. McKinnon, D. Jayatilaka, CrystEngComm2008, 10, 377.Google Scholar

  • [34]

    D. Jayatilaka, D. J. Grimwood, A. Lee, A. Lemay, A. J. Russel, C. Taylor, S. K. Wolff, P. Cassam-Chenai, A. Whitton. TONTO – A System for Computational Chemistry, 2005. Available at: http://hirshfeldsurface.net/.

  • [35]

    J. J. McKinnon, D. Jayatilaka, M. A. Spackman, Chem. Commun. 2007, 3814.Google Scholar

  • [36]

    A. L. Rohl, M. Moret, W. Kaminsky, K. Claborn, J. J. Mackinon, B. Kahr, Cryst. Growth Des. 2008, 8, 4517.CrossrefGoogle Scholar

About the article

Received: 2018-10-22

Accepted: 2018-11-28

Published Online: 2018-12-11

Published in Print: 2019-05-27


Citation Information: Zeitschrift für Kristallographie - Crystalline Materials, Volume 234, Issue 5, Pages 341–349, ISSN (Online) 2196-7105, ISSN (Print) 2194-4946, DOI: https://doi.org/10.1515/zkri-2018-2141.

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