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BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

Mean Amplitudes of Vibration, Thermodynamic Functions, Molecular Polarizability and Absolute Raman Intensities of Σ+g Modes in Carbon Subnitride

  • G. Nagarajan , E. R. Lippincott and J. M. Stutman

Vibrational and structural informations for carbon subnitride, a molecule possessing a linear symmetrical structure with the point group D∞h, have been used to determine the mean-square amplitude quantities and mean amplitudes of vibration for the bonded and nonbonded atom pairs at the temperatures T=0 and T=298°K by the Cyvin method. The molar thermodynamic functions have been computed for the temperature range 100-6000°K on the basis of a rigid rotator, harmonic oscillator model. Bond polarizabilities, molecular polarizability and polarizability deriva­tives corresponding to absolute Raman intensities of Σg+ modes in the ground electronic state have been calculated by the Lippincott-Stutman method employing the delta-function potentials

Published Online: 2014-6-2
Published in Print: 1965-6-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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