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In this paper we show that there exist rather simple aromatic systems which show no line narrowing in their fluorescence at 2 K, when excited with narrow bandwidth. However, large inhomogeneous line broadening is detected via a shift of the fluorescence bands with excitation energy. This inhomogenous broadening is attributed to a quasi-continuous site splitting, which is present up to about 240 K. The influence of high excess energy on the inhomogenous broadening is dis-cussed.
Received: 1976-07-12
Published Online: 2014-06-02
Published in Print: 1976-10-01
Citation Information: Zeitschrift für Naturforschung A, Volume 31, Issue 10, Pages 1220–1227, ISSN (Online) 1865-7109, ISSN (Print) 0932-0784, DOI: https://doi.org/10.1515/zna-1976-1014.
© 1946 – 2014: Verlag der Zeitschrift für Naturforschung. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0
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