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Zeitschrift für Naturforschung A

A Journal of Physical Sciences

Editor-in-Chief: Holthaus, Martin

Editorial Board: Fetecau, Corina / Kiefer, Claus


IMPACT FACTOR 2017: 1.414

CiteScore 2018: 1.15

SCImago Journal Rank (SJR) 2018: 0.370
Source Normalized Impact per Paper (SNIP) 2018: 0.431

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0932-0784
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Volume 31, Issue 12

Issues

Infrared-Microwave Double Resonance and Double Photon Transitions in FCN

Harold Jones
Published Online: 2014-06-02 | DOI: https://doi.org/10.1515/zna-1976-1224

Abstract

The utility of a conventional microwave spectrometer in determining the relative disposition of a CO2 -laser line and a molecular transition and ultimately the exact frequency of an infrared transition, is demonstrated by making use of three non-linear spectroscopic effects, high frequency Stark effect, IR-MW double resonance and IR-MW double photon transitions. New situations are encountered in the production of the double photon transitions and the observation of the high frequency Stark effect. From a combination of the double photon transitions with double resonance signals produced in single d. c. Stark components it was concluded that the R (2) transition of the υ1 band of the linear molecule FCN lies 104 ± 15 MHz lower in frequency than the R(20), 9.4 μm CO2 -laser line i.e. R(2) transition = 1079.58711 ± 0.0005 cm-1 .

About the article

Received: 1976-11-12

Published Online: 2014-06-02

Published in Print: 1976-12-01


Citation Information: Zeitschrift für Naturforschung A, Volume 31, Issue 12, Pages 1614–1619, ISSN (Online) 1865-7109, ISSN (Print) 0932-0784, DOI: https://doi.org/10.1515/zna-1976-1224.

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© 1946 – 2014: Verlag der Zeitschrift für Naturforschung. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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[4]
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