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Zeitschrift für Naturforschung A

A Journal of Physical Sciences

Editor-in-Chief: Holthaus, Martin

Editorial Board: Fetecau, Corina / Kiefer, Claus


IMPACT FACTOR 2016: 1.432

CiteScore 2017: 1.30

SCImago Journal Rank (SJR) 2017: 0.403
Source Normalized Impact per Paper (SNIP) 2017: 0.632

Online
ISSN
1865-7109
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Volume 31, Issue 12

Issues

Near Infrared Absorption of Ethylene between 8200 cm-1 and 9500 cm-1 to High Pressures and Temperatures

F. W. Nees / M. Buback
Published Online: 2014-06-02 | DOI: https://doi.org/10.1515/zna-1976-1236

Abstract

The near infrared absorption of pure ethylene in the region of the second overtone of the C-H stretching fundamentals (8200 cm-1 to 9500 cm-1) was measured at supercritical temperatures (Tc = 9.5 °C) between 22 °C and 200 °C from 0.7 bar to 3000 bar.

The density and temperature dependence of bandshape, maximum frequency and absorption intensity are reported and discussed. The bands observed within a wide range of experimental conditions are assigned to combination and overtone modes.

The molar integrated intensity B̅λ determined between the wavelength of maximum absorption and the high frequency absorption boundary was observed to be independent of pressure and temperature. This enables spectroscopic concentration determinations on ethylene in high pressure - high temperature phase equilibria and reactions.

About the article

Received: 1976-10-19

Published Online: 2014-06-02

Published in Print: 1976-12-01


Citation Information: Zeitschrift für Naturforschung A, Volume 31, Issue 12, Pages 1690–1695, ISSN (Online) 1865-7109, ISSN (Print) 0932-0784, DOI: https://doi.org/10.1515/zna-1976-1236.

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© 1946 – 2014: Verlag der Zeitschrift für Naturforschung. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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