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Zeitschrift für Naturforschung A

A Journal of Physical Sciences

Editor-in-Chief: Holthaus, Martin

Editorial Board: Fetecau, Corina / Kiefer, Claus

IMPACT FACTOR 2016: 1.432

CiteScore 2017: 1.30

SCImago Journal Rank (SJR) 2017: 0.403
Source Normalized Impact per Paper (SNIP) 2017: 0.632

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Volume 31, Issue 12


Investigation of the 1H Spin-Lattice Relaxation in Polycrystalline NH4ReO4 Induced by Mechanical Sample Rotation

H. Rager
Published Online: 2014-06-02 | DOI: https://doi.org/10.1515/zna-1976-1239


Measurements of the proton spin-lattice relaxation time, T1 , in polycrystalline NH4ReO4 have shown that mechanical sample rotation in the static magnetic field reduces T1 for proton magnetic resonance frequencies within the range 30 - 42 MHz. The rotation induced proton spin-lattice relaxation times, T1, were measured at different Larmor frequencies, sample rotation frequencies, and temperatures. At room temperature T1 increases with increasing proton Larmor frequency. The dependence of T1 on sample rotation frequency and temperature is small. The "normal" proton T1 times were determined as a function of temperature at 30 and 42 MHz. From these measurements an average activation energy of 2.4 kcal/mole was obtained for the NH4+ reorientation. The "normal" spin-lattice relaxation behavior was observed to be non-exponential at 30 MHz above 200 K and at 42 MHz above 260 K and is nearly independent on temperature above 300 K.

About the article

Received: 1976-11-08

Published Online: 2014-06-02

Published in Print: 1976-12-01

Citation Information: Zeitschrift für Naturforschung A, Volume 31, Issue 12, Pages 1707–1710, ISSN (Online) 1865-7109, ISSN (Print) 0932-0784, DOI: https://doi.org/10.1515/zna-1976-1239.

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© 1946 – 2014: Verlag der Zeitschrift für Naturforschung. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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