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Zeitschrift für Naturforschung A

A Journal of Physical Sciences

Editor-in-Chief: Holthaus, Martin

Editorial Board Member: Fetecau, Corina / Kiefer, Claus / Röpke, Gerd / Steeb, Willi-Hans

12 Issues per year


IMPACT FACTOR 2016: 1.432

Cite Score 2016: 1.35

SCImago Journal Rank (SJR) 2016: 0.368
Source Normalized Impact per Paper (SNIP) 2016: 0.594

Online
ISSN
1865-7109
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Volume 32, Issue 12 (Dec 1977)

Issues

The High Resolution Rotational Spectrum of Silylbromide, SiH381Br

K.-F. Dössel / D. H. Sutter
Published Online: 2014-06-02 | DOI: https://doi.org/10.1515/zna-1977-1217

Abstract

The microwave spectrum of SiH381Br has been reanalysed in the frequency range 8-40 GHz under high resolution. From 64 observed hyperfine transitions improved values for the rotational constant B = 4292646.2(4) kHz and the quadrupole coupling constant eqQ = 279825(5) kHz were obtained. Furthermore the centrifugal distortion constants DJ = 1.81(1) kHz and DJK = 29.19(4) kHz and the spin-rotation constants CN = -2.32(40) kHz and CK = -34.2(11) kHz were determined. From the values of CN and CK the 81Br nuclear shielding tensor is calculated. An improved value of ∣μ∣ - 1.319(8) D is given for the molecular electric dipole-moment.

About the article

Received: 1977-08-15

Published Online: 2014-06-02

Published in Print: 1977-12-01


Citation Information: Zeitschrift für Naturforschung A, ISSN (Online) 1865-7109, ISSN (Print) 0932-0784, DOI: https://doi.org/10.1515/zna-1977-1217.

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© 1946 – 2014: Verlag der Zeitschrift für Naturforschung. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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