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Zeitschrift für Naturforschung A

A Journal of Physical Sciences

Editor-in-Chief: Holthaus, Martin

Editorial Board: Fetecau, Corina / Kiefer, Claus


IMPACT FACTOR 2017: 1.414

CiteScore 2018: 1.15

SCImago Journal Rank (SJR) 2018: 0.370
Source Normalized Impact per Paper (SNIP) 2018: 0.431

Online
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1865-7109
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Volume 36, Issue 12

Issues

Internal Rotation Spectrum in the Ground State of cis Propionyl Fluoride

F. Scappini
  • Corresponding author
  • Institut für Physikalische Chemie, Abteilung Chemische Physik, Kiel, West Germany
  • Other articles by this author:
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/ H. Dreizler
Published Online: 2014-06-02 | DOI: https://doi.org/10.1515/zna-1981-1210

Abstract

The microwave ground state spectrum of cis propionyl fluoride has been investigated expanding, with respect to a previous study, the range of the quantum numbers of the transitions, J up to 40 and K up to 18. At low K the spectrum resembles that of an asymmetric rigid rotor, except in a number of cases where the lines are split into A, E doublets. At intermediate and high K the mixing of the if-doublet rigid rotor wave functions makes forbidden transitions appear. The results of the analysis of the methyl top internal rotation ground state splittings are: V3 = 2350 ± 11 cal/mole, ≮ (i, a) = 32.7° ±2.0°, and Iα = 3.18 ± 0.03 uÅ2.

About the article

Received: 1981-10-23

Published Online: 2014-06-02

Published in Print: 1981-12-01


Citation Information: Zeitschrift für Naturforschung A, Volume 36, Issue 12, Pages 1327–1333, ISSN (Online) 1865-7109, ISSN (Print) 0932-0784, DOI: https://doi.org/10.1515/zna-1981-1210.

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© 1946 – 2014: Verlag der Zeitschrift für Naturforschung. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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