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Zeitschrift für Naturforschung A

A Journal of Physical Sciences

Editor-in-Chief: Holthaus, Martin

Editorial Board: Fetecau, Corina / Kiefer, Claus


IMPACT FACTOR 2017: 1.414

CiteScore 2018: 1.15

SCImago Journal Rank (SJR) 2018: 0.370
Source Normalized Impact per Paper (SNIP) 2018: 0.431

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ISSN
1865-7109
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Volume 36, Issue 12

Issues

Fluorescence from High Vibronically Excited Benzene: a "Channel Three" Problem

L. Wunsch
  • Corresponding author
  • Institut für Physikalische und Theoretische Chemie, Technische Universität München, Garching, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ H. J. Neusser
  • Institut für Physikalische und Theoretische Chemie, Technische Universität München, Garching, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
/ E. W. Schlag
  • Institut für Physikalische und Theoretische Chemie, Technische Universität München, Garching, Germany
  • Other articles by this author:
  • De Gruyter OnlineGoogle Scholar
Published Online: 2014-06-02 | DOI: https://doi.org/10.1515/zna-1981-1213

Abstract

Gas phase benzene is excited by two-photon absorption at various pressures between 4 and 80 torr. Fluorescence is observed even from states located at excess energies of 3000 cm-1 - 7000 cm-1 , i.e. well above the onset of "channel three". The nonradiative decay rates as estimated from this fluorescence intensity continue the well known shortening of lifetime with excess energy in a monotone fashion and do not show a drastic cut-off as often concluded from previous line-width measurements.

About the article

Received: 1981-11-11

Published Online: 2014-06-02

Published in Print: 1981-12-01


Citation Information: Zeitschrift für Naturforschung A, Volume 36, Issue 12, Pages 1340–1343, ISSN (Online) 1865-7109, ISSN (Print) 0932-0784, DOI: https://doi.org/10.1515/zna-1981-1213.

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© 1946 – 2014: Verlag der Zeitschrift für Naturforschung. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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