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Zeitschrift für Naturforschung A

A Journal of Physical Sciences

Editor-in-Chief: Holthaus, Martin

Editorial Board: Fetecau, Corina / Kiefer, Claus


IMPACT FACTOR 2017: 1.414

CiteScore 2018: 1.15

SCImago Journal Rank (SJR) 2018: 0.370
Source Normalized Impact per Paper (SNIP) 2018: 0.431

Online
ISSN
1865-7109
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Volume 36, Issue 12

Issues

Die Kinetik des Zerfalls von tert. Butylperoxypivalat bei hohen Drücken und Temperaturen / The Kinetics of the Decomposition of tert.Butylperoxypivalate up to High Pressures and Temperatures

M. Buback / H. Lendle
Published Online: 2014-06-02 | DOI: https://doi.org/10.1515/zna-1981-1219

Abstract

The decomposition of tert. butylperoxypivalate dissolved in n-heptane has been measured ir-spectroscopically in optical high-pressure cells up to 2000 bar at temperatures between 65 °C and 105 °C. The reaction follows a first order rate law with an activation energy Ea = 122.3 ±3.0 kJ · mol-1 and an activation volume ⊿V = 1.6 ± 1.0 cm3 mol-1 .

About the article

Received: 1981-11-12

Published Online: 2014-06-02

Published in Print: 1981-12-01


Citation Information: Zeitschrift für Naturforschung A, Volume 36, Issue 12, Pages 1371–1377, ISSN (Online) 1865-7109, ISSN (Print) 0932-0784, DOI: https://doi.org/10.1515/zna-1981-1219.

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© 1946 – 2014: Verlag der Zeitschrift für Naturforschung. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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