The kinetics of the Ce4+-decay and the formation of CO2 are measured in sulfuric acid solutions of malonic acid. The reaction rate is slowed down by Ce3+ -ions due to a reaction of Ce3+ with malonic acid radicals. The primary source of CO2 is the decarboxylation of malonic acid radicals. Implications on the mechanism of the BZ reaction are discussed.
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Zeitschrift für Naturforschung A
A Journal of Physical Sciences
Editor-in-Chief: Holthaus, Martin
Editorial Board: Fetecau, Corina / Kiefer, Claus
12 Issues per year
IMPACT FACTOR 2016: 1.432
CiteScore 2017: 1.30
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Volume 29 (1974)
- Issue 12 (Dec 1974) , pp. 1699-1948
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Volume 28 (1973)
- Issue 12 (Dec 1973) , pp. 1875-1982
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Volume 27 (1972)
- Issue 12 (Dec 1972) , pp. 1695-1876
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- Issue 10 (Oct 1972) , pp. 1383-1538
- Issue 8-9 (Sep 1972) , pp. 1167-1381
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Volume 26 (1971)
- Issue 12 (Dec 1971) , pp. 1941-2090
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Volume 25 (1970)
- Issue 12 (Dec 1970) , pp. 1773-i
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Volume 24 (1969)
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- Issue 11 (Nov 1969) , pp. 1675-1858
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- Issue 9 (Sep 1969) , pp. 1291-1431
- Issue 8 (Aug 1969) , pp. 1163-1290
- Issue 7 (Jul 1969) , pp. 1037-1162
- Issue 6 (Jun 1969) , pp. 871-1035
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- Issue 4 (Apr 1969) , pp. 495-690
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Volume 23 (1968)
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Volume 21 (1966)
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- Issue 1-2 (Feb 1966) , pp. 1-186
Volume 20 (1965)
- Issue 12 (Dec 1965) , pp. 1537-1734
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Volume 19 (1964)
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Volume 18 (1963)
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Volume 17 (1962)
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Volume 16 (1961)
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Volume 15 (1960)
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Volume 14 (1959)
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Volume 13 (1958)
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Volume 12 (1957)
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Volume 9 (1954)
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Issue 1 (Jan 1950) , pp. 1-64
Walther Kossel, Zu Max...
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Zum 60. Geburtstag von...
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Werner Heisenberg, Arn...
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- Wechselwirkung von Neutronen mit Wolfram und seinen Isotopen
- Hall Effect, or Hyperbolic Magnetohydrodynamics, HMHD
- Photoacoustic Effect on Liquids Characterized by Transport Phenomena
- Lattice Vibrations, MIR and FIR Optical Properties of Boron and Icosahedral Boron-Rich Borides I. Alpha-Rhombohedral Structure Group
- Probenpotentialmodulation zur Spektroskopie elektronenangeregter Auger-Elektronen mit einem Gegenfeldanalysator
- Comparison of Variational Solutions of the Thomas-Fermi Model in Terms of the Corrected Ionization Energy
- Spin I = 1 NMR Patterns for the Case of Twofold Internal Spin Interactions
- Gauche Propanal: Microwave Spectrum and Methyl Barrier
- Oxidation of Malonic Acid by Ceric Ions Subset of the Belousov-Zhabotinsky Reaction
- EPR Characterisation of Bis(dimethylglyoximato)-Cobalt(II) Complexes and Their Oxygen Adducts Synthesised in an X-Zeolite Matrix
- Electronic Structure and Photophysical Characteristics of Substituted 3-(2-Benzthiazolyl)-Coumarins and Coumarinimines
- Bifurcation and Stability Analysis of a One-Dimensional Diffusion-Autocatalytic Reaction System
- X-ray Structural Analysis of Molten LiF — LiCl System
- Luminescence Quenching of Rhodamines by Cyclooctatetraene
- Self-Diffusion of Sodium, Chloride and Iodide Ions in Acetonitrile-Water Mixtures
- Internal Mobilities in the Molten Binary System (K,Rb)NO
- Internal Cation Mobilities in the Molten Binary Systems KNO-Sr(NO) and KNO-Ba(NO)
- Origin of Biomolecular Chirality. Analysis of Frank’s Model
- Ab initio and Semiempirical Studies on HC-B=O and H-B=O. Their Structure and Vibrational Spectra
- Na , Al, and V Multinuclear NMR-Imaging and NMR-Spectroscopy with a 1.5 T Imager
- Phosphoreszenzeigensch aften von Methyl-, Chlor- und Brom-Derivaten des [2.2] Paracyclophans
- Determination of Quadrupole and Spin-Rotation Coupling in the Rotational Spectrum of Carbonylsulfide-S and -O
Oxidation of Malonic Acid by Ceric Ions Subset of the Belousov-Zhabotinsky Reaction
H.D. Försterling
- Fachbereich Physikalische Chemie, Philipps-Universität, D-3550 Marburg
- Other articles by this author:
- De Gruyter OnlineGoogle Scholar
- Fachbereich Physikalische Chemie, Philipps-Universität, D-3550 Marburg
- Other articles by this author:
- De Gruyter OnlineGoogle Scholar
- Fachbereich Physikalische Chemie, Philipps-Universität, D-3550 Marburg
- Other articles by this author:
- De Gruyter OnlineGoogle Scholar
Published Online: 2014-06-02 | DOI: https://doi.org/10.1515/zna-1987-0909
Open Access
Keywords: Belousov-Zhabotinsky Reaction; Malonic Acid; Malonic Acid Radical; CO2; Ce4+
About the article
Received: 1987-07-10
Published Online: 2014-06-02
Published in Print: 1987-09-01
Citation Information: Zeitschrift für Naturforschung A, Volume 42, Issue 9, Pages 963–969, ISSN (Online) 1865-7109, ISSN (Print) 0932-0784, DOI: https://doi.org/10.1515/zna-1987-0909.
© 1946 – 2014: Verlag der Zeitschrift für Naturforschung. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0
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Richard J. Field
Modern Physics Letters B, 2015, Volume 29, Number 34, Page 1530015
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- Photoacoustic Effect on Liquids Characterized by Transport Phenomena
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- Spin I = 1 NMR Patterns for the Case of Twofold Internal Spin Interactions
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- Phosphoreszenzeigensch aften von Methyl-, Chlor- und Brom-Derivaten des [2.2] Paracyclophans
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