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Zeitschrift für Naturforschung A

A Journal of Physical Sciences

Editor-in-Chief: Holthaus, Martin

Editorial Board: Fetecau, Corina / Kiefer, Claus

IMPACT FACTOR 2017: 1.414

CiteScore 2018: 1.15

SCImago Journal Rank (SJR) 2018: 0.370
Source Normalized Impact per Paper (SNIP) 2018: 0.431

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Volume 49, Issue 1-2


Nuclear Quadrupole Interaction and Ionic Dynamics in Sodium Superionic Conductors

Nobuo Nakamura
Published Online: 2014-06-02 | DOI: https://doi.org/10.1515/zna-1994-1-249


Recent work on the 23N a quadrupole interaction in the NASICON family is reviewed. The applicability and the limitation of the two-dimensional nutation NMR to complex systems with more than one quadrupolar nuclear sites is discussed and the possibility of sodium ion exchange in some of the NASICON-type com pounds is pointed out. The microscopic mechanism of the site exchange is examined by molecular dynamics simulation. A model potential energy function for the site exchange and /or hopping transport o f the sodium ions is proposed. It interprets qualitatively the difference between the activation energies deduced by NMR and by conductivity measurement.

Keywords : Nutation NMR; Quadrupole effect; Superionic conductor; NASICON; Chemical ex­change; Molecular dynamics

About the article

Received: 1993-10-23

Published Online: 2014-06-02

Published in Print: 1994-02-01

Citation Information: Zeitschrift für Naturforschung A, Volume 49, Issue 1-2, Pages 337–344, ISSN (Online) 1865-7109, ISSN (Print) 0932-0784, DOI: https://doi.org/10.1515/zna-1994-1-249.

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© 1946 – 2014: Verlag der Zeitschrift für Naturforschung. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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