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BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

1H, 2H and 13C NMR Studies of Cation Dynamics in a Layered Perovskite-Type Incommensurate Compound (n-C3H7NH3)2CdCl4

  • Koh-ichi Suzuki EMAIL logo , Hiroki Fujimori , Tetsuo Asaji , Shin’ichi Ishimaru and Ryuichi Ikeda

Cation dynamics in (n-C3H7NH3)2CdCl4 and (n-C3H7ND3)2CdCl4 were investigated by 1H, 2H, and 13C NMR measurements. An overall motion of the cation being associated with the fluctuation of the molecular axis is suggested to be activated with increasing temperature. The cationic motion is enhanced at the counter side of the -NH3+ group probably because the group is bound with the inorganic layer through the N-H...Cl hydrogen bonds

Received: 2001-12-17
Published Online: 2014-6-2
Published in Print: 2002-7-1

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This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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