The thermal stability of FeS2 cathode material for thermal batteries is investigated in the LiCl-KCl eutectic containing up to 10 wt% Li2O (used as anti-peak). The results show that the decomposition of pyrite shifts to higher temperatures in the presence of molten salts as the S2 gas is repressed by the liquid phase. For high lithium oxide contents the decomposition temperature of pyrite decreases by 100 °C. In addition Li2FeS2 as reaction product is evidenced whereas Li3Fe2S4 is expected from literature data.
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Zeitschrift für Naturforschung A
A Journal of Physical Sciences
Editor-in-Chief: Holthaus, Martin
Editorial Board: Fetecau, Corina / Kiefer, Claus
12 Issues per year
IMPACT FACTOR 2016: 1.432
CiteScore 2017: 1.30
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- Issue 1-2 (Feb 1966) , pp. 1-186
Volume 20 (1965)
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Volume 19 (1964)
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Volume 18 (1963)
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Volume 17 (1962)
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Volume 16 (1961)
- Issue 12 (Dec 1961) , pp. 1265-1412
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Volume 15 (1960)
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Volume 14 (1959)
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Volume 13 (1958)
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Volume 11 (1956)
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Volume 8 (1953)
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Issue 1 (Jan 1950) , pp. 1-64
Walther Kossel, Zu Max...
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Zum 60. Geburtstag von...
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Lise Meitner, Otto Hah...
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- Approximate Solutions for Conservative Nonlinear Oscillators by He’s Homotopy Method
- Application of the Variational Iteration Method to Nonlinear Volterra’s Integro-Differential Equations
- Existence and Blow up of Solutions of the Cauchy Problem of the Generalized Damped Multidimensional Improved Modified Boussinesq Equation
- Fractional Diffusion Equation in Cylindrical Symmetry: A New Derivation
- Fourier-Bessel Expansions of Electromagnetic Fields in Chiral Cylindrical Structures
- The Analysis Approach of Boundary Layer Equations of Power-Law Fluids of Second Grade
- On Convergence Generation in Computing the Electro-Magnetic Casimir Force
- Nonlinear Instability of Rayleigh-Taylor Waves Subjected to Time-Dependent Temperatures
- Effect of Doping Concentration on ZnMnO Thin Films Grown by RF Magnetron Sputtering
- A Gated Four Probe Technique for Field Effect Measurements on Disordered Organic Semiconductors
- Thermal Stability of FeS Cathode Material in “Thermal” Batteries: Effect of Dissolved Oxides in Molten Salt Electrolytes
- Substituent Effects on the Hydrolysis of p-Substituted Benzonitriles in Sulfuric Acid Solutions at (25.0± 0.1) °C
- Investigation of the Local Lattice Structure and the Effects of the Orbital Reduction Factor on the g Factors of a Trigonal [Ni(HO)] Cluster in NiTiF · 6HO and ZnSiF · 6HO Crystals at Different Temperatures
- Energy Levels and g Factors of Cu-Doped Bis(L-asparaginato)zinc(II)
Thermal Stability of FeS2 Cathode Material in “Thermal” Batteries: Effect of Dissolved Oxides in Molten Salt Electrolytes
Patrick J. Masset
- Karl Winnacker Institut der Dechema e.V., Theodor-Heuss Allee 25, D-60486 Frankfurt am Main, Germany
- Other articles by this author:
- De Gruyter OnlineGoogle Scholar
Published Online: 2014-06-02 | DOI: https://doi.org/10.1515/zna-2008-0911
Open Access
Keywords : Thermal Batteries; Electrolyte; Pyrite; Oxide; Molten Salt; LiCl-KCl Eutectic
About the article
Received: 2008-03-04
Published Online: 2014-06-02
Published in Print: 2008-09-01
Citation Information: Zeitschrift für Naturforschung A, Volume 63, Issue 9, Pages 596–602, ISSN (Online) 1865-7109, ISSN (Print) 0932-0784, DOI: https://doi.org/10.1515/zna-2008-0911.
© 1946 – 2014: Verlag der Zeitschrift für Naturforschung. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0
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- Approximate Solutions for Conservative Nonlinear Oscillators by He’s Homotopy Method
- Application of the Variational Iteration Method to Nonlinear Volterra’s Integro-Differential Equations
- Existence and Blow up of Solutions of the Cauchy Problem of the Generalized Damped Multidimensional Improved Modified Boussinesq Equation
- Fractional Diffusion Equation in Cylindrical Symmetry: A New Derivation
- Fourier-Bessel Expansions of Electromagnetic Fields in Chiral Cylindrical Structures
- The Analysis Approach of Boundary Layer Equations of Power-Law Fluids of Second Grade
- On Convergence Generation in Computing the Electro-Magnetic Casimir Force
- Nonlinear Instability of Rayleigh-Taylor Waves Subjected to Time-Dependent Temperatures
- Effect of Doping Concentration on Zn1-XMnxO Thin Films Grown by RF Magnetron Sputtering
- A Gated Four Probe Technique for Field Effect Measurements on Disordered Organic Semiconductors
- Thermal Stability of FeS2 Cathode Material in “Thermal” Batteries: Effect of Dissolved Oxides in Molten Salt Electrolytes
- Substituent Effects on the Hydrolysis of p-Substituted Benzonitriles in Sulfuric Acid Solutions at (25.0± 0.1) °C
- Investigation of the Local Lattice Structure and the Effects of the Orbital Reduction Factor on the g Factors of a Trigonal [Ni(H2O)6]2+ Cluster in NiTiF6 · 6H2O and ZnSiF6 · 6H2O Crystals at Different Temperatures
- Energy Levels and g Factors of Cu2+-Doped Bis(L-asparaginato)zinc(II)
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