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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

IMPACT FACTOR 2017: 0.757

CiteScore 2017: 0.68

SCImago Journal Rank (SJR) 2017: 0.277
Source Normalized Impact per Paper (SNIP) 2017: 0.394

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Volume 27, Issue 1


The Nephelauxetic Effect — Calculation and Accuracy of the Interelectronic Repulsion Parameters

II. Application to d3 and d7 Single Crystal Spectra at Cryogenic Temperatures

E. König
  • Institut für Physikalische Chemie II, Universität Erlangen-Nürnberg, 8520 Erlangen, Germany
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Published Online: 2014-06-02 | DOI: https://doi.org/10.1515/znb-1972-0102

Expressions are reviewed which may be used to determine 10 Dq and B from the spin-allowed bands in the optical spectra of d3 and d7 electron systems within octahedral and tetrahedral sym metry. Application to low-temperature single crystal spectra demonstrates that (i) the semi-empirical ligand field theory reproduces transition energies with sufficient accuracy; (ii) differences in the values of 10 Dq and B observed with different fitting methods may be attributed to the inaccuracy of experimental data; (iii) there are generally valid values of B35 and β35 for each complex ion.

About the article

Received: 1971-09-28

Published Online: 2014-06-02

Published in Print: 1972-01-01

Citation Information: Zeitschrift für Naturforschung B, Volume 27, Issue 1, Pages 1–6, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-1972-0102.

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© 1946 – 2014: Verlag der Zeitschrift für Naturforschung. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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