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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

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IMPACT FACTOR 2016: 0.631

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Volume 31, Issue 7 (Jul 1976)


Über Galvinole und Galvinoxyle, II EPR-HFS- und elektronen-spektroskopische Untersuchung von Galvinoxyl-Mehrspinsystemen.

On Galvinols and Galvinoxyls, II EPR and Electronic Absorption Spectra of Oligo Galvinoxyl Radicals in Solution

W. Gierke / W. Harrer / B. Kibste / H. Kurreck / J. Reusch
Published Online: 2014-06-02 | DOI: https://doi.org/10.1515/znb-1976-0714

The synthesis of several so far unknown mono- and oligo-galvinols and galvinoxyls is described. The ESR hyperfine splitting measurements in liquid solution indicate that the spin exchange frequency is greater than the hyperfine splitting in the galvinoxyl biradicals (J≫a). The electronic absorption spectra of the galvinols and galvinoxyls are discussed taking into account the different prototropic and redox equilibria, respectively. Using magnetic susceptibility measurements the singlet-triplet and doublet-quartet splitting is studied.

About the article

Received: 1976-03-05

Published Online: 2014-06-02

Published in Print: 1976-07-01

Citation Information: Zeitschrift für Naturforschung B, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-1976-0714.

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© 1946 – 2014: Verlag der Zeitschrift für Naturforschung. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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