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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

12 Issues per year


IMPACT FACTOR 2016: 0.631

SCImago Journal Rank (SJR) 2016: 0.237
Source Normalized Impact per Paper (SNIP) 2016: 0.332

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1865-7117
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Volume 31, Issue 7

Issues

Über Galvinole und Galvinoxyle, III. EPR-Spektroskopie an regellos orientierten Bis-Galvinoxyl-Biradikalen in der Glasmatrix / On Galvinols and Galvinoxyls, III. EPR Study of Zero Field Splitting in Randomly Oriented Galvinoxyl Biradicals

W. Broser / B. Kirste / H. Kurreck / J. Reusch / M. Plato
Published Online: 2014-06-02 | DOI: https://doi.org/10.1515/znb-1976-0715

ESR powder spectra of several differently bridged bis-galvinoxyl biradicals have been recorded. The spectra can be interpreted in terms of a weak electron-electron dipolar coupling between the unpaired spins of randomly oriented triplet molecules. Using MO-theory and a point charge model for atomic orbitals a detailed structural analysis is performed on the basis of quantum mechanical calculations. Taking into account the twist angles between the various aryl rings the experimental data can be explained satisfactorily.

About the article

Received: 1976-03-05

Published Online: 2014-06-02

Published in Print: 1976-07-01


Citation Information: Zeitschrift für Naturforschung B, Volume 31, Issue 7, Pages 974–980, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-1976-0715.

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© 1946 – 2014: Verlag der Zeitschrift für Naturforschung. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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[1]
W. BROSER, B. KIRSTE, H. KURRECK, J. REUSCH, and M. PLATO
Chemischer Informationsdienst, 1976, Volume 7, Number 43, Page no

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