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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

12 Issues per year


IMPACT FACTOR 2017: 0.757

CiteScore 2017: 0.68

SCImago Journal Rank (SJR) 2017: 0.277
Source Normalized Impact per Paper (SNIP) 2017: 0.394

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ISSN
1865-7117
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Volume 33, Issue 4

Issues

Novel Aspects in the Preparation of Phorone

Maria Konieczny / George Sosnovsky
Published Online: 2014-06-02 | DOI: https://doi.org/10.1515/znb-1978-0421

Abstract

The condensation of acetone using anhydrous hydrogen chloride results after three weeks at room temperature, in a 15% yield of phorone (4) and a 75% yield of mesityl oxide (5). In the presence of one weight percent of the Lewis acid, aluminium chloride, the yield of 4 is increased to 39%. An increase in the amount of the Lewis acid, aluminium chloride, to ten weight percent results in a 22% yield of phorone (4) and a 68% yield of mesityl oxide (5). In the presence of one hundred weight percent of aluminium chloride,

in the absence of hydrogen chloride, the condensation produces a 62% yield of mesityl oxide (5) and no phorone (4). In the course of this investigation, two intermediates, 6 and 7

were isolated and characterized for the first time. These intermediates are the actual products formed in the condensation of acetone with hydrogen chloride, and not the “free” phorone (4) and mesityl oxide (5). The conversion of 6 and 7 to 5 and 4, respectively, occurs during the isolation stage using a saturated solution of ethanolic potassium hydroxide.

Keywords: Phorone; Mesityl Oxide; Triacetoneamine; Nitroxyls

About the article

Received: 1978-01-04

Published Online: 2014-06-02

Published in Print: 1978-04-01


Citation Information: Zeitschrift für Naturforschung B, Volume 33, Issue 4, Pages 454–460, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-1978-0421.

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© 1946 – 2014: Verlag der Zeitschrift für Naturforschung. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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[1]
M. KONIECZNY and G. SOSNOVSKY
Chemischer Informationsdienst, 1978, Volume 9, Number 29

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