Jump to ContentJump to Main Navigation
Show Summary Details
More options …

Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

IMPACT FACTOR 2017: 0.757

CiteScore 2017: 0.68

SCImago Journal Rank (SJR) 2017: 0.277
Source Normalized Impact per Paper (SNIP) 2017: 0.394

See all formats and pricing
More options …
Volume 33, Issue 7


Kristallisationsvorgänge bei melallreichen Rubidiumoxiden / Crystallisation Processes in Metal Rich Rubidium Oxides

H. J. Deiseroth / A. Simon
Published Online: 2014-06-02 | DOI: https://doi.org/10.1515/znb-1978-0706


On the basis of X-ray investigations a structural model for the orientational disorder of Rb9O2 clusters in the rubidium suboxide Rb6O is derived, which is in accordance with details of the thermal analysis of the ordering process.

In the second part the thermal and structural investigations of a metastable phase of the probable composition Rb6,33O are described. The phase is formed by warming quenched samples RbxO (9 >x > 7) to co. 140 K and decomposes at ca. 183 K. Its cubic structure bears relationships to the structure of rubidium as well as to YB66 (replacing B12 icosahedra in the latter compound by Rb atoms).

A special DTA instrument used for the investigation of Rb6,33O is described.

: Alkali Metals; Crystal Structures; Metastable Phases; Suboxides; Thermal Analysis

About the article

Received: 1978-04-04

Published Online: 2014-06-02

Published in Print: 1978-07-01

Citation Information: Zeitschrift für Naturforschung B, Volume 33, Issue 7, Pages 714–722, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-1978-0706.

Export Citation

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

Citing Articles

Here you can find all Crossref-listed publications in which this article is cited. If you would like to receive automatic email messages as soon as this article is cited in other publications, simply activate the “Citation Alert” on the top of this page.

Arndt Simon
Angewandte Chemie, 1988, Volume 100, Number 1, Page 163

Comments (0)

Please log in or register to comment.
Log in