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BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

Fluorhaltige Nitrile als Komplexliganden / Fluorine Containing Nitriles as Complex Ligands

  • Rolf Froböse , Rüdiger Mews and Oskar Glemser

N-Cyano-sulfurdifluoride-imide NC-NSF2 and N-cyano-sulfuroxide-difluoride-imide NC-NSOF2 will react with AsFs to give the N-bonded nitrile adducts F5As · NC-NSF2 (F5As · NC-NSOF2). With [M(CO)5SO2]+AsF6- (M=Mn,Re) the expected complexes [(CO)5MNC-NSF2]+AsF6-

[(CO)5MNC-NSF2]+AsF6-are formed in quantitative yield.

Received: 1979-6-18
Published Online: 2014-6-2
Published in Print: 1979-10-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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