N-Cyano-sulfurdifluoride-imide NC-NSF2 and N-cyano-sulfuroxide-difluoride-imide NC-NSOF2 will react with AsFs to give the N-bonded nitrile adducts F5As · NC-NSF2 (F5As · NC-NSOF2). With [M(CO)5SO2]+AsF6- (M=Mn,Re) the expected complexes [(CO)5MNC-NSF2]+AsF6-
[(CO)5MNC-NSF2]+AsF6-are formed in quantitative yield.
Keywords: N -Cyano -sulfurdifluoride -imide; N-Cyano -sulfuroxide -difluoride-imide; Arsenic Pentafluoride; Nitrilo-pentacarbonyl-manganese Hexafluoroarsenates; Nitrilo-pentacarbonyl-rhenium Hexafluoroarsenates
Received: 1979-6-18
Published Online: 2014-6-2
Published in Print: 1979-10-1
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