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Zeitschrift für Naturforschung B

A Journal of Chemical Sciences

12 Issues per year


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1865-7117
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Volume 34, Issue 11

Issues

Kristallstruktur von Mangan(II)sulfit-Trihydrat, α-MnSO3·3H2O / Crystal Structure of Manganese(II)sulfite Trihydrate, α-MnSO3·3H2O

B. Engelen
  • Laboratorium für Anorganische Chemie der Gesamthochschule Siegen, Adolf-Reichwein-Straße, D-5900 Siegen 21
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/ C. Freiburg
Published Online: 2014-06-02 | DOI: https://doi.org/10.1515/znb-1979-1104

Abstract

The structure of α-MnSO3·3H2O, space group P21/n, Z = 4, Dm = 2.42, Dx = 2.425gcm-3, a = 6.6501(3), b = 8.9065(4), c = 8.7925(4) Å, β=96.105(3)°, was solved by the Patterson method and refined by Fourier and least-squares methods. All H atoms were located. The final R’s are 2.1/3.2% for the 1749 observed/2280 measured reflexions. Coordination of Mn is octahedral involving O atoms from three water molecules and three different sulfite groups. MnO6 octahedra are linked through sulfite sulfur. The Mn-O distances range from 2.149(2) to 2.314(2) Å. The S-O distances of the sulfite group are 1.529(2), 1.529(2) and 1.544(2) Å. The first two are elongated by one, the latter by two H bonds. The O-S-O angles are 103.25(9), 104.18(9) and 104.35(9)°.

: X-ray; Sulfites; Sulfite Hydrates

About the article

Received: 1979-07-09

Published Online: 2014-06-02

Published in Print: 1979-11-01


Citation Information: Zeitschrift für Naturforschung B, Volume 34, Issue 11, Pages 1495–1499, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-1979-1104.

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© 1946 – 2014: Verlag der Zeitschrift für Naturforschung. This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License. BY-NC-ND 3.0

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[1]
H. D. Lutz, W. Buchmeier, W. Eckers, and B. Engelen
Zeitschrift f�r anorganische und allgemeine Chemie, 1983, Volume 496, Number 1, Page 21
[2]
H. D. Lutz, W. Eckers, and B. Engelen
Zeitschrift f�r anorganische und allgemeine Chemie, 1981, Volume 475, Number 4, Page 165
[3]
Brendan F. Abrahams, Carmel T. Abrahams, Marissa G. Haywood, Timothy A. Hudson, Boujemaa Moubaraki, Keith S. Murray, and Richard Robson
Dalton Transactions, 2012, Volume 41, Number 14, Page 4091

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