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BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

Chemistry of Alkoxo Complexes, Part III *Synthesis and Characterization of Some Mono(carboxylato)mono (alkoxo)nickel(II) Complexes

  • B. P. Baranwal , G. K. Parashar and R. C. Mehrotra

Abstract

A number of mono(carboxylato)mono(alkoxo)nickel(II) complexes of the general formula, Ni(OR)(OOCR′), (with R′ = C13H27, C15H35 and C17H35) have been synthesized (where R = Me and Pri) by the reactions of nickel methoxide and isopropoxide with the respective carboxylic acids in equimolar ratio and (where R = Et and But) by alcohol interchange reactions. A study of the molecular weight, infra-red and electronic reflectance spectra and magnetic susceptibility in addition to elemental analyses has been carried out to throw some light on the probable structure of these derivatives.

Received: 1978-11-29
Published Online: 2014-6-2
Published in Print: 1979-3-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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