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BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

Darstellung und Kristallstruktur von SbCl3I2 ·1.4-Dithian/Preparation and Crystal Structure of SbCl3 · I2 · 1,4-Dithiane

  • Gertrud Kiel

Abstract

The darkred compound SbCl3 · I2 · S2C4H8 has been prepared and its crystal structure determined. This new compound crystallizes in the monoclinic system, space group P21, with a = 849.2 pm, b = 904.2 pm, c = 923.6 pm and β = 106.1° at a temperature of 113 K, and with a = 858.8(2) pm, b = 914.7(3) pm, c = 934.0(4) pm and β = 106.62(3)° at a temperature of 293 K, respectively. The structure is built up from chains (SC2H4S···I-I-ClSbCl2)∞ with a ψ-trigonal bipyramid around Sb.

Received: 1980-8-19
Revised: 1980-10-22
Published Online: 2014-6-2
Published in Print: 1981-1-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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