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BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

Ein Triarsanato(1.3)-Chelat des Titans / A Triarsanato(1,3) Chelate of Titanium

  • Hartmut Köpf and Ulrich Gorges

Abstract

When the cyclopentaarsane (AsC2H5)6 is reacted in a 1:2 or 1:5 molar ratio with metallic potassium in THF, soluble dipotassium catenaarsanes of the assumed stoichiometry K2(ASC2H5)5 (1) or K2(ASC2H5)2 (2), respectively, are formed. On reaction with (C5H5)2TiCl2 in THF, both the red 1 or the greenish 2 lead to the same dark-brown, airsensitive triarsanato complex (C5H5)2Ti(AsC2H5)3 (3).

Received: 1981-4-30
Published Online: 2014-6-2
Published in Print: 1981-10-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

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