Skip to content
BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

Zur Hochdruckpolymorphie von Bal2 / High Pressure Polymorphism of Bal2

  • H. P. Beck

Abstract

High pressure investigations of Bal2 yielded a new polymorph, which could be quenched and characterized by X-ray methods. PbCl2-type Bal2 is converted to an anti-Fe2P-type structure with more regular coordination polyhedra and an increase in effective coordination numbers. We discuss changes in bonding type by comparing the Madelung part of lattice energy in the two polymorphs.

Received: 1981-5-22
Published Online: 2014-6-2
Published in Print: 1981-10-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

This work is licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 3.0 License.

Downloaded on 19.3.2024 from https://www.degruyter.com/document/doi/10.1515/znb-1981-1013/html
Scroll to top button