Tetraalkyldibismutane/Tetraalkyldibismutanes

Hans Joachim Breunig; Ditmar Müller

doi:10.1515/znb-1983-0202

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Zeitschrift für Naturforschung B

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Tetraalkyldibismutane/Tetraalkyldibismutanes

Hans Joachim Breunig

Universität Bremen, Fachbereich 2 (Chemie), Postfach 330440, D-2800 Bremen 33
Other articles by this author:
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/ Ditmar Müller

Universität Bremen, Fachbereich 2 (Chemie), Postfach 330440, D-2800 Bremen 33
Other articles by this author:
De Gruyter Online Google Scholar

Published Online: 2014-06-02 | DOI: https://doi.org/10.1515/znb-1983-0202

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Abstract

The tetraalkyldibismutanes R₂BiBiR₂ (R = Et, Pr, iPr, Bu) were synthesized by reactions of 1,2-dibromoethane with sodium dialkylbismutides, which were produced by cleavage of the corresponding trialkylbismutanes with sodium in liquid ammonia. The dibismutanes were isolated in good yields as air sensitive red liquids. Spectral data of dibismutanes and some bismutanes are compared with data of their antimony analogues. ¹H NMR spectra reveal, that the methylene protons in Et₄Bi₂ as well as the methyl groups in iPr₄Bi₂ are diastereotopic.

Keywords: Tetraethyldibismutane; Tetrapropyldibismutane; Tetraisopropyldibismutane; Tetrabutyldibismutane; Triisopropylbismutane

About the article

Received: 1982-09-27

Revised: 1982-11-22

Published Online: 2014-06-02

Published in Print: 1983-02-01

Citation Information: Zeitschrift für Naturforschung B, Volume 38, Issue 2, Pages 125–129, ISSN (Online) 1865-7117, ISSN (Print) 0932-0776, DOI: https://doi.org/10.1515/znb-1983-0202.

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[1]

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[2]

A unique Bi–Bi bond forming reaction using organobismuth oxides and phosphorus compounds bearing a P(O)H group

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[3]

Organobismuth(III) and Dibismuthine Complexes Bearing N,N′-Disubstituted 1,8-Diaminonaphthalene Ligand: Synthesis, Structure, and Reactivity

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[4]

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[5]

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Synthesis and Structure of Bis- and Tris-Benzyl Bismuth Complexes

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DOI: 10.1021/om5010786

[7]

Temperature-Dependent Electron Shuffle in Molecular Group 13/15 Intermetallic Complexes

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Temperature-Dependent Electron Shuffle in Molecular Group 13/15 Intermetallic Complexes

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[12]

Chapter 5

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Tetraalkyldibismutane/Tetraalkyldibismutanes

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