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BY-NC-ND 3.0 license Open Access Published by De Gruyter June 2, 2014

Organometallphosphin-substituierte Übergangsmetallkomplexe, XIX [1] Carbonyl-dinitrosyl-organometallphosphin-eisen-Komplexe / Organometalphosphine-substituted Transition Metal Complexes, XIX [1] Carbonyl Dinitrosyl Organometalphosphine Iron Complexes

  • Herbert Schumann , Karl-Heinz Köhricht and Manfred Meißner

Abstract

The reactions of dicarbonyl dinitrosyl iron with tri-tert-butylphosphine, di(feri-butyl)-trimethylsilyl-, -germyl-, -stannyl-phosphine, tert-butyl-bis(trimethylsilyl)-, -(germyl)-, -(stannyl)phosphine, as well as with tris(trimethylsilyl)-, -(germyl)-, and -(stannyl)phosphine result in the elimination of one CO ligand and the formation of the corresponding carbonyl dinitrosyl organometalphosphine iron complexes. The IR, 1H, 31P, 13C, and 119Sn NMR spectra of the new complexes are reported and discussed.

Received: 1983-2-22
Published Online: 2014-6-2
Published in Print: 1983-6-1

© 1946 – 2014: Verlag der Zeitschrift für Naturforschung

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